Cover Image

Triple molybdates one-, one - and three(two)valence metals

G. E. Khaikina, S. F. Solodovnikov, O. M. Basovich, Z. A. Solodovnikova, Yu. M. Kadyrova, A. A. Savina, E. S. Zolotova, V. N. Yudin, T. S. Spiridonova

Abstract


The review summarizes experimental data on the phase formation, structure and properties of new complex oxide compounds group – triple molybdates containing tetrahedral molybdate ion, two different singly charged cation, together with tri- or divalent cation. The several structural families of these compounds were distinguished and it shown that many of them are of interest as luminescent, laser, ion-conducting or nonlinear optical materials.

Keywords


triple molybdates; one-; two - and trivalent metals; phase formation; structure; functional properties

Full Text:

PDF

References


Trunov VK, Efremov VA, Velikodnyy YuA. Kristallokhimiya i svoystva dvoynykh molybdatov i vol'framatov [Crystallochemistry and properties of double molybdates and wolframates]. Leningrad (USSR): Nauka; 1986. 173 p. Russian.

Evdokimov AA, Efremov VA, Trunov VK, Kleyman IA, Tananaev IV. Soedineniya redkozemel'nykh elementov. Molibdaty, vol'framaty [Rare-earth elements' compounds. Molibdates, wolframates]. Moscow: Nauka; 1991. 267 p. Russian.

Kaminskiy AA, Aminov LK, Ermolaev VL, Kornienko AA, Kravchenko EB, Malkin BZ, Mill' BV, Perlin YuE, Petrosyan AG, Pekhov KK, Sakun VP, Sarkisov SE, Sveshnikova EB, Skripko GA, Starostin NV, Shkadarevich AP. Fizika i spektroskopiya lazernykh kristallov [Physics and spectroscopy of lazer crystals]. Moscow: Nauka; 1986. 272 p. Russian.

Isupov VA. Binary molybdates and tungstates of mono- and trivalent elements as possible ferroelastics and ferroelectrics. Ferroelectrics. 2005;321:63–90. doi:10.1080/00150190500259699

Isupov VA. Ferroelectric and ferroelastic phase transitions in molybdates and tungstates of monovalent and bivalent elements. Ferroelectrics. 2005;322:83–114. doi:10.1080/00150190500315574

Khaikina EG, Bazarova ZhG, Solodovnikov SF, Klevtsova RF. Troynye molibdaty kak osnova novykh perspektivnykh slozhnooksidnykh materialov. Inzhenernaya ekologiya. 2011;1:48-9. Russian.

Basovich OM, Khaikina EG, Solodovnikov SF, Tsyrenova GD. Phase formation in the systems Li2MoO4–K2MoO4–Ln2(MoO4)3 (Ln = La, Nd, Dy, Er) and properties of triple molybdates LiKLn2(MoO4)4. J Solid State Chem. 2005;178(5):1580–8. doi:10.1016/j.jssc.2004.12.016

Basovich OM, Khaikina EG, Vasil'ev EV, Frolov AM. Fazoobrazovanie v sistemakh Li2MoO4–Rb2MoO4–Ln2(MoO4)3 i svoystva LiRbLn2(MoO4)4. Zhurnal neorganicheskoy khimii. 1995;40(12):2047-51. Russian.

Basovich OM, Khaikina EG. Fazovye ravnovesiya v sisteme Li2MoO4–Tl2MoO4–Pr2(MoO4)3. Zhurnal neorganicheskoy khimii. 2000;45(9):1542–4.

Kadyrova YuM. Fazoobrazovanie, sintez i stroenie novykh soedineniy v sistemakh M2MoO4–R2(MoO4)3 i Li2MoO4–M2MoO4–R2(MoO4)3 (M - shchelochnoy metall; R = In, Sc, Fe, Ga, Cr, Al) [dissertation]. Ulan-Ude (Russia); 2010. 148 p. Russian.

Basovich OM, Khaikina EG. Formation laws for scheelite-like triple molybdates LiMLn2(MoO4)4. Russ J Inorg Chem. 2006;51(7):1182–6. doi:10.1134/S0036023606070114

Szillat H, Müller-Buschbaum Hk. Synthese und Kristallstruktur von KCuHoMo4O16. Z Naturforsch. 1994;49:350–4. German.

Müller-Buschbaum Hk, Gallinat St. Synthese und Röntgenstrukturanalyse von KCuGd2Mo4O16 und KCuTb2Mo4O16. Z Naturforsch. 1995;50:1794–8. German.

Klevtsova RF, Glinskaya LA, Alekseev VI, Khalbaeva KM, Khaikina EG. Crystal structural study of ternary molybdate LiRbBi2(MoO4)4. J Struct Chem. 1994;34(5):789-93. doi:10.1007/BF00753581

Khal'baeva KM, Khaikina EG. Subsolidusnoe stroenie sistemy Li2MoO4–Tl2MoO4–Bi2(MoO4)3. Zhurnal neorganicheskoy khimii. 2000;45(2):314–9. Russian.

Morozov VA, Lazoryak BI, Smirnov VA, Mikhailin VV, Basovich OM, Khaikina EG. Kristallicheskie struktury i lyuminestsentnye svoystva troynykh molibdatov LiMNd2(MoO4)4 (M = K, Rb, Tl). Zhurnal neorganicheskoy khimii. 2001;46(6):977–82. Russian.

Klevtsova RF, Vasil'ev AD, Glinskaya LA, Kruglik AI, Kozhevnikova NM, Korsun VP. Kristallostrukturnoe issledovanie troynykh molibdatov sostava Li3Ba2Ln3(MoO4)8, Ln = Gd, Tm. Zhurnal strukturnoy khimii. 1992;33(3):126–30. Russian.

Kiseleva II, Sirota MI, Ozerov RI, Balakireva TP, Mayer AA. Dvoynye molibdaty bariy-lantanoidov, BaLn2(MoO4)4. Kristallografiya. 1979;24(6):1277–9. Russian.

Bravina S, Morozovsky N, Pasechnik L, Khaikina E, Budnyk O. Characteristic behaviour of electric parameters of mesoporous materials under humidity impact. In: Abstracts of 9th European Conference on Applications of Polar Dielectrics ECAPD-9. 2008; Rome, Italy. p. 208.

Bravina SL, Morozovsky NV, Khaikina EG, Boukherroub R, Dogheche E, Remiens D, Basovich OM, Kadyrova YuM. Electrophysical study of fast humidity sensing of nano- and mesoporous media. In: Materialy Vserossiyskoy nauchnoy konferentsii s mezhdunarodnym uchastiem "Baykal'skiy materialovedcheskiy forum". 2012 Jul 9-13; Ulan-Ude, Russia. p. 23-5.

Yakovlev VG, Mikhailin VV, Romanenko AYu, Zaushitsyn AV, Basovich OM, Khaikina EG. Spektral'no-lyuminestsentnye svoystva LiRbLa2–xEux(MoO4)4. Vestnik MGU Seriya 3 Fizika Astronomiya. 2010;5:56–9. Russian.

Xie A, Yuan XM, Wang FX. A potential red-emitting phosphors scheelite-like triple molybdates LiKGd2(MoO4)4: Eu3+ for white light emitting diode applications. Sci China Techol Sci. 2011; 54(1): 70–75. doi:10.1007/s11431-010-4222-y

Mueller M, Hildmann BO, Hahn Th. Structure of Cs6Zn5(MoO4)8. Acta Crystallogr. 1987;C43(2):184–6. doi:10.1107/s0108270187096501

Solodovnikov SF, Klevtsov PV, Glinskaya LA, Klevtsova RF. Sintez i kristallicheskaya struktura tseziy-tsinkovogo molibdata Cs6Zn5(MoO4)8 = 2Cs3(Zn5/61/6)3(MoO4)4. Kristallografiya. 1987;32(3):618–22. Russian.

Khal’baeva KM, Solodovnikov SF, Khaikina EG, Kadyrova YuM, Solodovnikova ZA, Basovich OM. Phase formation in the Li2MoO4–K2MoO4–In2(MoO4)3 system and crystal structures of new compounds K3InMo4O15 and LiK2In(MoO4)3. J Solid State Chem. 2012;87:276–81. doi:10.1016/j.jssc.2012.01.010

Khal'baeva KM, Solodovnikov SF, Khaikina EG, Kadyrova YuM, Solodovnikova ZA, Basovich OM. Phase formation in the Li2MoO4–Rb2MoO4–Fe2(MoO4)3 system and crystal structure of a novel triple molybdate LiRb2Fe(MoO4)3. J Solid State Chem. 2013;203:227–31. doi:10.1016/jjssc.2013.04.020

Solodovnikov SF, Solodovnikova ZA, Kadyrova YuM, Khaikina EG, Basovich OM. Fazoobrazovanie v sisteme Li2MoO4–Cs2MoO4–Al2(MoO4)3 i kristallicheskaya struktura LiCs4Al(MoO4)4. In: Materialy Vserossiyskoy nauchnoy konferentsii s mezhdunarodnym uchastiem "Baykal'skiy materialovedcheskiy forum". 2012 Jul 9-13; Ulan-Ude, Russia. p. 141-2. Russian.

Khaikina EG, Basovich OM, Khal'baeva KM. Fazoobrazovanie v serebrosoderzhashchikh molibdatnykh sistemakh s uchastiem trekhvalentnykh metallov. In: Tezisy dokladov III Vserossiyskoy nauchnoy konferentsii po fiziko-khimicheskomu analizu. 2007 Apr 12-14; Makhachkala, Russia. p. 39-41. Russian.

Khal'baeva KM, Khaikina EG, Basovich OM. Fazovye ravnovesiya v molibdatnykh sistemakh litiya-serebra(natriya)-vismuta. Zhurnal neorganicheskoy khimii. 2005;50(8):1380–2.

Khaikina EG. Sintez, osobennosti fazoobrazovaniya i stroeniya dvoynykh i troynykh molibdatov odno- i trekhvalentnykh metallov [dissertation]. Ulan-Ude (Russia); 2008. 446 p. Russian.

Savina AA. Sintez, stroenie i svoystva novykh soedineniy v sistemakh Na2MoO4–Cs2MoO4–R2(MoO4)3 (R – trekhvalentnyy metall) [dissertation]. Ulan-Ude (Russia); 2013. 169 p. Russian.

Basovich OM, Osokina AN, Khaikina EG, Solodovnikov SF, Spiridonova TS, Solodovnikova ZA. Fazoobrazovanie v sistemakh Ag2MoO4–Cs2MoO4–R2(MoO4)3 (R = Bi, Nd, Yb, Lu, In, Sc). In: Tezisy dokladov Shkoly-konferentsii molodykh uchenykh "Neorganicheskie soedineniya i funktsional'nye materialy (ICFM-2015)". 2015; Novosibirsk, Russia. p. 81. Russian.

Solodovnikov SF. Osobennosti fazoobrazovaniya i kristallokhimii dvoynykh molibdatov i volframatov shchelochnikh i dvukhvalentnykh metallov i soputstvuyushchikh im faz [dissertation]. Novosibirsk; 2000. 424 p. Russian.

Kozhevnikova NM, Mokhosoev MV. Troynye molibdaty. Ulan-Ude (Russia): Izdatel'stvo Buryatskogo gosuniversiteta; 2000. 297 p. Russian.

Uskova AA, Basovich OM, Solodovnikov SF, Podkorytova YuO, Solodovnikova ZA, Khaikina EG. Poisk i issledovanie troynykh molibdatov s tseziem i trekhvalentnymi metallami. In: Materialy Vserossiyskoy molodezhnoy nauchno-prakticheskoy konferentsii s mezhdunarodnym uchastiem "Ekologobezopasnye i resursosberegayushchie tekhnologii i materialy". 2011 May 12-14; Ulan-Ude, Russia. p. 57–9. Russian.

Basovich OM, Uskova AA, Solodovnikov SF, Solodovnikova ZA, Khaikina EG. Fazoobrazovanie v sistemakh Na2MoO4–Cs2MoO4–Ln2(MoO4)3 i kristallicheskaya struktura novogo troynogo molibdata Cs7Na5Yb2(MoO4)9. Vestnik Buryatskogo gosuniversiteta, Vypusk 3, Khimiya, Fizika. 2011:24-9. Russian.

Savina AA, Atuchin VV, Solodovnikov SF, Solodovnikova ZA, Krylov AS, Maximovskiy EA, Molokeev MS, Oreshonkov AS, Pugachev AM, Khaikina EG. Synthesis, structural and spectroscopic properties of acentric triple molybdate Cs2NaBi(MoO4)3. J Solid State Chem. 2015;225:53–8. doi:10.1016/j.jssc.2014.11.023

Savina AA, Solodovnikov SF, Belov DA, Basovich OM, Solodovnikova ZA, Gudkova IA, Stefanovich SYu, Lazoryak BI, Khaikina EG. Novye ionoprovodyashchie troynye molibdaty s allyuoditopodobnoy strukturoy. In: Ekologobezopasnye i resursosberegayushchie tekhnologii i materialy. II Vserossiyskaya molodezhnaya nauchnaya konferentsiya s mezhdunarodnym uchastiem. 2014 May 15-16; Ulan-Ude, Russia. p. 93-4. Russian.

Savina AA, Solodovnikov SF, Belov DA, Basovich OM, Solodovnikova ZA, Pokholok KV, Stefanovich SYu, Lazoryak BI, Khaikina EG. Synthesis, crystal structure and properties of alluaudite-like triple molybdate Na25Cs8Fe5(MoO4)24. J Solid State Chem. 2014;220:217–20. doi:10.1016/j.ssc.2014.09.004

Moore PB. Crystal chemistry of the alluaudite structure type: contribution to the paragenesis of pegmatite phosphate giant crystals. Amer. Miner. 1971;56(11–12):1955. Available from: http://www.minsocam.org/ammin/AM56/AM56_1955.pdf

Solodovnikova ZA, Solodovnikov SF, Zolotova ES. New triple molybdates Cs3LiCo2(MoO4)4 and Rb3LiZn2(MoO4)4, filled derivatives of the Cs6Zn5(MoO4)8 type. Acta crystallogr. 2006;C62(1):i6-8. doi:10.1107/S0108270105037121

Solodovnikov SF, Khaikina EG, Solodovnikova ZA, Kadyrova YuM, Khal’baeva KM, Zolotova ES. Novye semeystva litiysoderzhashchikh troynykh molibdatov i stabiliziruyushchaya rol' litiya v ikh strukturoobrazovanii. Doklady RAN. 2007;416(1):60–5. Russian.

Solodovnikova ZA. Fazoobrazovanie i stroenie troynykh molibdatov i soputstvuyushchikh soedineniy v sistemakh Li2MoO4–A+2MoO4–M2+MoO4 (A+ = K, Rb, Cs; M2+ = Mg, Mn, Co, Ni, Zn) [dissertation]. Novosibirsk (Russia); 2008. 219 p. Russian.

Solodovnikova ZA, Solodovnikov SF, Gudkova IA, Zolotova ES. Sintez i stroenie novykh troynykh molibdatov K3NaM4(MoO4)6 (M = Ni, Mg, Co). In: Materialy Vserossiyskoy nauchnoy konferentsii s mezhdunarodnym uchastiem "Baykal'skiy materialovedcheskiy forum". 2012 Jul 9-13; Ulan-Ude, Russia. p. 143-4. Russian.

Solodovnikov SF, Solodovnikova ZA, Zolotova ES, Yudin VN, Gudkova IA, Kadyrova YuM, Khaikina EG. Troynye molibdaty (vol'framaty) semeystva Cs6Zn5(MoO4)8. In: Tezisy dokladov 9-go seminara SO RAN - UrO RAN "Termodinamika i materialovedenie", posvyashchennogo pamyati akademika F.A. Kuznetsova. 2014 Jun 30 - Jul 4; Novosibirsk, Russia. p. 108. Russian.

Yudin VN, Zolotova ES, Solodovnikova ZA, Solodovnikov SF, Gudkova IA. Fazoobrazovanie i stroenie troynykh molibdatov v sisteme Cs2MoO4–Na2MoO4–MnMoO4. In: Tezisy dokladov 9-go seminara SO RAN - UrO RAN "Termodinamika i materialovedenie", posvyashchennogo pamyati akademika F.A. Kuznetsova. 2014 Jun 30 - Jul 4; Novosibirsk, Russia. p. 151. Russian.

Yudin VN, Zolotova ES, Shkerin SN, Tolkacheva AS, Uporov SA, Solodovnikova ZA, Solodovnikov SF. Stroenie i svoystva troynykh molibdatov CsNa5M3(MoO4)6 (M = Ni, Co, Mn). In: Materialy Vserossiyskoy nauchnoy konferentsii s mezhdunarodnym uchastiem "II Baykal'skiy materialovedcheskiy forum". 2015 Jun 29 - Jul 5; Ulan-Ude, Russia. p. 146-8. Russian.

Yudin VN, Zolotova ES, Solodovnikova ZA, Solodovnikov SF, Tolkacheva AS. Fazoobrazovanie, stroenie i svoystva troynykh molibdatov v sisteme Cs2MoO4–Na2MoO4–CoMoO4. In: Tezisy dokladov Shkoly-konferentsii molodykh uchenykh "Neorganicheskie soedineniya i funktsional'nye materialy (ICFM-2015)". 2015; Novosibirsk, Russia. p. 139. Russian.

D’Yvoire F, Bretey E, Collin G. Crystal structure, non-stoichiometry and conductivity of II-Na3M2(AsO4)3 (M = Al, Ga, Cr, Fe). Solid State Ionics. 1988;28–30:1259–64. doi:10.1016/0167-2738(88)90367-0

Zolotova ES, Solodovnikova ZA, Yudin VN, Solodovnikov SF, Khaikina EG, Basovich OM, Korolkov IV, Filatova IYu. Phase relations in the Na2MoO4-Cs2MoO4 and Na2MoO4-Cs2MoO4-ZnMoO4 systems, crystal structures of Cs3Na(MoO4)2 and Cs3NaZn2(MoO4)4. J Solid State Chem. Forthcoming 2015.

Gudkova IA. Fazovye ravnovesiya, sintez, stroenie i svoystva soedineniy, obrazuyushchikhsya v troynykh sistemakh Li2MoO4–A2MoO4–MMoO4 (A = Na, K, Rb, Cs; M = Ca, Sr, Pb, Ba, Cd) [dissertation]. Novosibirsk (Russia); 2014. 192 p. Russian.




DOI: http://dx.doi.org/10.15826/chimtech.2015.2.4.032

Copyright (c) 2015 G. E. Khaikina, S. F. Solodovnikov, O. M. Basovich, Z. A. Solodovnikova, Y. M. Kadyrova, A. A. Savina, E. S. Zolotova, V. N. Yudin, T. S. Spiridonova

© Chimica Techno Acta, 2014-2019
ISSN 2411-1414 (Online), ISSN 2409-5613 (Print)

ROAD logo WorldCat logo DOAJ logo CAS logo BASE logo eLibrary logo