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Materials based on BIFEVOX and bismuth or iron simple oxides nanopowders

A. A. Krylov, Yu. V. Emelyanova, E. S. Buyanova, M. V. Morozova, A. I. Vylkov, A. Yu. Chuykin


Compositions of composite materials based on BIFEVOX and nanopowders of bismuth and iron oxides have been obtained. The absence of chemical interaction between the components has been proved, the total electrical conductivity of materials in the average temperature region has been determined. It has been shown that under the selected formation conditions, it has not yet been possible to achieve significant improvement of the functional characteristics of heterogeneous compositions in comparison with individual phases. However positive results on chemical and structural stability give way to further investigations.


BIMEVOX; oxygen-ion conductors; electrical conductivity; impedance spectroscopy

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Garcia-Gonzalez E, Arribas M, Gonzalez-Calbet JM. Short-Range-Long-Range Order Transformation in the Bi4V2–xFexO11–y Series. Chem Mater. 2001;13(1):96–102. doi:10.1021/cm0003929

Buyanova ES, Petrova SA, Emel’yanova YuV, Blinova AL, Morozova MV, Zhukovskii VM, Zhuravlev VD. Preparation, Structure, and Charge Transport Characteristics of BIFEVOX Ultrafine Powders. Russ J Inorg Chem. 2009;54(8):1193–204. doi:10.1134/S0036023609080051

Pena V, Rivera A, Leon C, Santamaria J, Garcia-Gonzalez E, Gonzalez-Calbet JM. Correlated Oxygen Diffusion in BIFEVOX. Chem Mater. 2002;14(4):1606–9. doi:10.1021/cm010743z

Zhukovskii VM, Buyanova ES, Emel’yanova YuV, Morozova MV, Shafigina RR, Zakharov RG, Zhuravlev VD. Synthesis, Structure, and Conductivity of BIMEVOX Oxide Ceramics. Russ J Electrochem. 2009;45(5):512–9. doi:10.1134/S1023193509050024

Morozova MV, Buyanova ES, Emelyanova JuV, Zhukovskiy VM, Petrova SA. Highconducting oxide ceramics BIMEVOX: synthesis, structure, properties. Solid State Ionics. 2011;192(1):153–7. doi:10.1016/j.ssi.2010.04.020

Morozova MV, Buyanova ES, Petrova SA, Khisametdinova VV, Emel’yanova YuV, Shatokhina AN, Zhukovskii VM. Structural and Thermal Stability of BIMEVOX Oxygen Semiconductors. Russ J Electrochem. 2011;47(4):448–52. doi:10.1134/S1023193511040100

Rondao AIB, Patrıcio SG, Figueiredo FML, Marques FMB. Composite electrolytes for fuel cells: Long-term stability under variable atmosphere. Int J Hydrogen Energy. 2014;39:5460–9. doi:10.1016/j.ijhydene.2013.12.125.208

Fuierera P, Maiera M, Exner J, Moos R. Anisotropy and thermal stability of hot-forged BICUTIVOX oxygen ion conducting ceramics. J Eur Ceram Soc. 2014;34(4):943–51. doi:10.1016/j.jeurceramsoc.2013.10.016

Sunarso J, Baumann S, Serra JM, Meulenberg WA, Liu S, Lin YS, Diniz da Costa JC. Mixed ionic-electronic conducting (MIEC) ceramic-based membranes for oxygen separation. J Membrane Science. 2008;320(1-2):13–41. doi:10.1016/j.memsci.2008.03.074

Sabolsky EM, Razmyar S, Sabolsky K. Nano-ceria enhancement of Bi2Cu0.1V0.9O5.35 (BICUVOX) ceramic electrolytes. Mater Lett. 2012;76:47–50. doi:10.1016/j.matlet.2012.02.048

Piva RH, Piva DH, Venturini J, Floriano R, Morelli MR. Inhibition of order–disorder phase transition and improvements in the BICUVOX.1 properties by using yttria-stabilized zirconia particles. Ceram Int. 2014;41(1):171–7. doi:10.1016/j.ceramint.2014.08.055

Buyanova ES, Shafigina RR, Morozova MV, Emel’yanova YuV, Khisametdinova VV, Zhukovskii VM, Petrova SA, Tarakina NV. Electrochemical Characteristics, Thermal and Chemical Compatibility in the La0.7Sr0.3CoO3 Electrode-γ-BIFEVOX Electrolyte System. Russ J Inorg Chem. 2013;58(5):554–8. doi:10.1134/S0036023613050033

Sammes NM, Tompsett GA, Näfe H, Aldinger F. Bismuth based oxide electrolytes—structure and ionic conductivity. J Eur Ceram Soc. 1999;19(10):1801–26. doi:10.1016/S0955-2219(99)00009-6

Kharton VV, Marques FMB, Atkinson A. Transport properties of solid oxide electrolyte ceramics: a brief review. Solid State Ionics. 2004;174:135–49. doi:10.1016/j.ssi.2004.06.015


Copyright (c) 2017 Krylov A.A., Emelyanova Yu.V., Buyanova E.S., Morozova M.V., Vylkov A.I., Chuykin A.Yu.

© Chimica Techno Acta, 2014-2018
ISSN 2411-1414 (Online), ISSN 2409-5613 (Print)

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