Graphical Abstract

Synthesis and research of photocurable protective coatings on the basis of olygoesteracrylates

O. A. Karsakova, M. V. Kuzmin

Abstract


In this work, photocurable protective coatings based on methacrylic acid esters have been developed and their physical and mechanical properties have been investigated. The photocurable compositions were obtained by mixing at different ratios the following methacrylic acid esters: polyethylene glycol dimethacrylate 400 and triethylene glycol dimethacrylate ether, polyethylene glycol dimethacrylate 400 and oligourethane dimethacrylate, polyethylene glycol dimethacrylate 400 and pentaerythritol tetraacrylate. For the obtained compositions, the viscosity was studied using a Brookfield rotary viscometer. To initiate polymerization, a mixture of initiators was used: benzoyl peroxide and benzoin. Curing of the obtained compositions was carried out under the influence of UV rays for 2-5 minutes. For photo-cured compositions, their physical and mechanical properties have been studied. It was found that the composition based on polyethylene glycol dimethacrylate modified with triethylene glycol dimethacrylate at a ratio of 70:30 has the highest strength.

Keywords


photocuring; protective coatings; polyethylene glycol dimethacrylate 400; triethylene glycol dimethacrylate ether; pentaerythritol tetraacrylate; oligourethane dimethacrylate; benzoyl peroxide; benzoin

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References


Deng L, Tang L, Qu J. Synthesis and photopolymerization of novel UV-curable macrophotoinitiators. Progress in Organic Coatings. 2020;141:105546. doi:10.1016/j.porgcoat.2020.105546

Quan H, Zhang T, Xu H, Luo Sh, Nie J, Zhu X. Photo-curing 3D printing technique and its challenges. Bioactive Materials. 2020;5(1):110–5. doi:10.1016/j.bioactmat.2019.12.003

Babkin O.E. Polimernye pokrytiya UF-otverzhdeniya [Polymer coatings of UV-curing]. Saint-Petersburg: Spbgukit, 2012. 39 p. Russian.




DOI: https://doi.org/10.15826/chimtech.2020.7.4.16

Copyright (c) 2020 O. A. Karsakova, M. V. Kuzmin

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Chimica Techno Acta, 2014-2024
ISSN 2411-1414 (Online)
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