In situ  synthesis, structural chemistry and vibrational  spectroscopy of Zn-doped Ca 5 Mg 4 (VO 4 ) 6

Anna S. Tolkacheva; Sergey N. Shkerin; Sofya A. Petrova; Olga M. Fedorova; Svetlana G. Titova; Ivan I. Leonidov

doi:10.15826/chimtech.2022.9.2.01

In situ synthesis, structural chemistry and vibrational spectroscopy of Zn-doped Ca₅Mg₄(VO₄)₆

Anna S. Tolkacheva, Sergey N. Shkerin, Sofya A. Petrova, Olga M. Fedorova, Svetlana G. Titova, Ivan I. Leonidov

Abstract

The phase formation of the solid solution Ca₅Mg_4–xZn_x(VO₄)₆ (0≤x≤4) was studied in situ using differential scanning calorimetry and high-temperature X-Ray powder diffraction (XRPD). XRPD analysis shows the appearance of unavoidable secondary pyrovanadate phases using conventional synthesis methods. The local structure of the solid solution was verified by vibrational spectroscopy. The analysis of the infrared and Raman spectroscopy data allows establishing the main features between vanadate garnets and their isostructural analogs among natural silicates.

Keywords

crystal structure, vibrational spectroscopy, X-ray diffraction, ceramics, differential scanning calorimetry, pyrovanadate, garnet

Full Text:

PDF

References

Mill BV, Ronniger G, Kabalov YuK. New garnet compounds A₃²⁺B₂²⁺C⁴⁺V₂⁵⁺O₁₂ (A = Ca, Cd; B = Mg, Zn, Co, Ni, Cu, Mn, Cd; C = Ge, Si). Russ J Inorg Chem. 2014;59:1208–1213. doi:10.1134/S0036023614110151

Ishi K, Ikuta Y. Isomorphous substitutions in vanadate garnets. N Jb Miner Abh. 2006;182:157–163. doi:10.1127/0077-7757/2006/0038

Yao GG, Liu P, Zhang HW. Novel series of low-firing microwave dielectric ceramics: Ca₅A₄(VO₄)₆ (A²⁺ = Mg, Zn). J Am Ceram Soc. 2013;96:1691–1693. doi:10.1111/jace.12359

Müller-Buschbaum Hk, von Postel M. Eine weitere Oxovanadat-Phase mit Granatstruktur: Ca₅Mg₃ZnV₆O₂₄. Z Anorg Allg Chem. 1992;615:101–103. doi:10.1002/zaac.19926150920

Krasnenko TI, Zolotukhina LV, Zabolotskaya EV, Svetlakov SV, Dobosh VG. Defect structure and electrical and magnetic properties of calcium manganese vanadium garnets. Inorg Mater. 1999;35:1179–1182.

Ronniger G, Mill BV. Vanadates with a defect garnet structure. Sov Phys Crystallogr. 1973;18:303–307.

Surat LL, Fotiev AA, Dobosh VG. V₂O₅–MgO–CaO–MnO(Mn₂O₃) system. Zh Neorg Khim. 1989;34:2924–2928.

Slobodin BV, Fotiev AA, Sharova NG. Phase composition of the CaO–MgO–V₂O₅ system. Zh Neorg Khim. 1977;23:184–187.

Li B, Zheng JG, Li W. Influence of cobalt ions non-stoichiometry on the microstructure and microwave properties of Ca₅Co₄(VO₄)₆ ceramics. Ceram Int. 2017;43:13956–13962. doi:10.1016/j.ceramint.2017.07.127

Li B, Tian J, Qiu L. Crystal structures and microwave dielectric properties of low-firing Ca₅Zn_4−xMg_xV₆O₂₄ ceramics. Ceram Int. 2018;44:18250–18255. doi:10.1016/j.ceramint.2018.07.035

Wang D, Xiang HC, Tang Y. Fang L, Khaliq J, Li CC. A low-ﬁring Ca₅Ni₄(VO₄)₆ ceramic with tunable microwave dielectric properties and chemical compatibility with Ag. Ceram Int. 2016;42:15094–15098. doi:10.1016/j.ceramint.2016.06.085

Fang L, Xiang F, Su CX, Zhang H. A novel low ﬁring micro-wave dielectric ceramic NaCa₂Mg₂V₃O₁₂. Ceram Int. 2013;39:9779–9783. doi:10.1016/j.ceramint.2013.05.041

Xiang HC, Fang L, Jiang XW, Li CC. Low-ﬁring and micro-wave dielectric properties of Na₂YMg₂V₃O₁₂ ceramic. Ceram Int. 2016;42:3701–3705. doi:10.1016/j.ceramint.2015.10.163

Yao GG, Liu P, Zhao XG, Zhou JP, Zhang HW. Low-temperature sintering and microwave dielectric properties of Ca₅Co₄(VO₄)₆ceramics. J Eur Ceram Soc. 2014;34:2983–2987. doi:10.1016/j.jeurceramsoc.2014.03.026

Pavitra E, Raju GSR, Park JY, Wang L, Moon BK, Yu JS. Novel rare-earth-free yellow Ca₅Zn_3.92In_0.08(V_0.99Ta_0.01O₄)₆ phosphors for dazzling white light-emitting diodes. Sci Rep. 2015;5:10296. doi:10.1038/srep10296

Li JF, Qiu KH, Li JF, Li W, Yang Q, Li JH. A novel broadband emission phosphor Ca₂KMg₂V₃O₁₂ for white light emitting diodes. Mater Res Bull. 2010;45:598–602. doi:10.1016/j.materresbull.2010.01.014

Song D, Guo CF, Zhao J, Suo H, Zhao XQ, Zhou XJ, Liu GZ. Host sensitized near-infrared emission in Nd³⁺-Yb³⁺ Co-doped Na₂GdMg₂V₃O₁₂ phosphor. Ceram Int. 2016;42:12988–12994. doi:10.1016/j.ceramint.2016.05.072

Dhobale AR, Mohapatra M, Natarajan V, Godbole SV. Synthesis and photoluminescence investigations of the white light emitting phosphor, vanadate garnet, Ca₂NaMg₂V₃O₁₂ co-doped with Dy and Sm. J Lumin. 2012;132:293–298. doi:10.1016/j.jlumin.2011.09.004

Leonidova ON, Patrakeev MV, Leonidov IA. Ionic and electronic transport in the garnet-type vanadate Ca_2.5Mg₂V₃O₁₂. J Solid State Electrochem. 2019;23:1083–1088. doi:10.1007/s10008-019-04202-y

Tolkacheva AS, Shkerin SN, Nikonov AV, Pershina SV, Khavlyuk PD, Leonidov II. Electrical and thermal properties of Ca₅Mg_4−xCo_x(VO₄)₆ (0≤x≤4), a promising electrode mate-rial. Mater. Lett. 2021;305:30811. doi:10.1016/j.matlet.2021.130811

Blanzat B, Loriers J. Synthese et etude des proprietes spectrales de monocristaux de vanadate a structure grenat Ca₂NaMg₂V₃O₁₂ active par l'europium trivalent. Mater Res Bull. 1974;9:1647–1654. doi:10.1016/0025-5408(74)90156-1

Dhanaraj G, Byrappa K, Prasad V, Dudley M. (Eds.). Springer Handbook of Crystal Growth. Heidelberg, Germany: Springer-Verlag GmbH; 2010. 1736 p.

Yu YM, Chani VI, Shimamura K, Inaba K, Fukuda T. Growth of vanadium garnet fiber crystals and variations of lattice parameter. J Cryst Growth 1997;177:74–78. doi:10.1016/S0022-0248(97)01070-1

Levina AA, Tadevosyan NO, Petrova SA, Buyanova ES, Morozova MV. Phase formation processes and synthesis of solid solutions in Ca–R–Nb–M–O systems. Chim Techno Acta. 2020;7:17–25. doi:10.15826/chimtech.2020.7.1.03

Klyndyuk AI, Chizhova EA, Shevchenko SV. Spin-state transition in the layered barium cobaltite derivatives and their thermoelectric properties. Chim Techno Acta. 2020;7:26–33. doi:10.15826/chimtech.2020.7.1.04

Klyndyuk AI, Zhuravleva YY, Gundilovich NN. Crystal structure, thermal and electrotransport properties of NdBa_1−xSr_xFeCo_0.5Cu_0.5O_5+δ (0.02≤x≤0.20) solid solutions. Chimica Techno Acta. 2021;8:20218301. doi:10.15826/chimtech.2021.8.3.01

Huang XY, Wang SY, Rtimi S, Devakumar B. KCa₂Mg₂V₃O₁₂: A novel efficient rare-earth-free self-activated yellow emitting phosphor. J Photochem Photobiol A Chem. 2020;401:112765. doi:10.1016/j.jphotochem.2020.112765

Tsirlin AA, Dikarev EV, Velikodny YA, Shpanchenko RV, Antipov EV. Pb_2.63Cd₂V₃O₁₂, a cation-deficient garnet-type vanadate. Acta Crystallogr C Struct Chem. 2007;63:140–142. doi:10.1107/S0108270107021233

Dutta U, Haque A, Seikh MM. Synthesis, structure and magnetic properties of Ti doped La₂MnNiO₆ double perovskite. Chim Techno Acta. 2019;6:80–92. doi:10.15826/chimtech.2019.6.3.01

Anokhina IA, Animitsa IE, Buzina AF, Voronin VI, Vykhodets VB, Kurennykh TЕ, Zaikov YP. Synthesis, structure and electrical properties of Li⁺-doped pyrochlore Gd₂Zr₂O₇. Chim Techno Acta. 2020;7:51–60. doi:10.15826/chimtech.2020.7.2.02

Park JY, Chung JW, Yang HK. Synthesis and photolumines-cence properties of yellow-emitting Ca₅(Zn_1−xMg_x)₄(VO₄)₆ self-activated phosphors. Optik. 2018;155:384–389. doi:10.1016/j.ijleo.2017.11.046

Tolkacheva AS, Shkerin SN, Zemlyanoi KG, Reznitskikh OG, Pershina SV, Khavlyuk PD. Thermal and electrical properties of Ca₅Mg_4−xZn_x(VO₄)₆ (0≤x≤4). J Therm Anal Calorim. 2019;136:1003–1009. doi:10.1007/s10973-018-7780-z

Lide DR. Handbook of Chemistry and Physics. 84th ed., Boca Raton, FL: CRC Press LLC; 2003. p. 4–93.

Powder Diffraction File PDF4+ ICDD 2018.

Petříček V, Dušek M, Palatinus L, Crystallographic computing system JANA2006: General features. Z. Kristallogr. 2014;229:345–352. doi:10.1515/zkri-2014-1737

Krasnenko TI, Zubkov VG, Tyutyunnik AP, Zolotukhina LV, Vasyutinskaya EF. Crystal structure of β′-Zn₂V₂O₇. Crystallogr. Rep. 2003;48:35–38. doi:10.1134/1.1541739

Miyauchi A, Okabe TH. Production of metallic vanadium by preform reduction process. Mater Trans. 2010;51(6):1102–1108. doi:10.2320/matertrans.M2010027

Shannon RD, Prewitt CT. Effective ionic radii in oxides and fluorides. Acta Crystallogr B Struct Sci Cryst Eng Mater. 1969;25:925–946. doi:10.1107/S0567740869003220

Fotiev AA. Vanadaty: Sostav, Sintez, Struktura, Svoĭstva [Vanadates: composition, synthesis, structure, properties] Moscow: Nauka; 1988. 272 p. Russian.

Rousseau DL, Bauman RP, Porto SPS. Normal mode determination in crystals. J Raman Spectrosc. 1981;10:253–290. doi:10.1002/jrs.1250100152

Koningstein JA, Mortensen OS. Laser-excited phonon Raman spectrum of garnets. J Mol Spectrosc. 1968;27:343-350. doi:10.1016/0022-2852(68)90043-X

Mingsheng P, Mao HK, Dien L, Chao ECT. Raman spectroscopy of garnet-group minerals. Chin J Geochem. 1994;13:176–183. doi:10.1007/BF02838517

Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordination Compounds. Part A: Theory and Applications in Inorganic Chemistry. 6th ed. Hoboken, NJ: John Wiley & Sons, Inc.; 2009. 419 p.

Kolesov BA, Geiger CA. Raman spectra of silicate garnets. Phys Chem Minerals. 1998;25:142–151. doi:10.1007/s002690050097

Moore RK, White WB, Long TV. Vibrational spectra of the common silicates: I. The garnets. Am. Mineral. 1971;56:54–71.

DOI: https://doi.org/10.15826/chimtech.2022.9.2.01

Copyright (c) 2021 Anna S. Tolkacheva, Sergey N. Shkerin, Sofya A. Petrova, Olga M. Fedorova, Svetlana G. Titova, Ivan I. Leonidov

This work is licensed under a Creative Commons Attribution 4.0 International License.

Chimica Techno Acta, 2014-2024
ISSN 2411-1414 (Online)
Copyright Notice

Username
Password
Remember me