Cover Image

Silica gel functionalized with imidazolium group via click chemistry – new stationary phase for ion chromatography

D. A. Chuprynina, I. A. Lupanova, V. V. Konshin, D. N. Konshina

Abstract


This manuscript describes the preparation of a simple effective ion-exchange material based on silica gel, on the surface of which methylimidazolium bromide is fixed using a click reaction. The resulting material was used as a stationary phase for the separation and determination of Cl, NO2, NO3, I, and SO42– using ion exchange chromatography. The separation efficiency and retention factors for the selected anions were studied in the pH range 3.5–6.5. The proposed material was used for the determination of Cl, SO42– in water and can be suggested for successful use in real water samples.


Keywords


click reaction, ion exchange, modified silica

Full Text:

PDF

References


Zatirakha AV, Smolenkov AD, Shpigun OA. Preparation and chromatographic performance of polymer-based anion exchangers for ion chromatography. Anal Chim Acta. 2016;904:33–50. doi:10.1016/j.aca.2015.11.012

Alpert AA, Regnier FE. Preparation of a porous microparticulatee anion-exchange chromatography support for proteins. J Chromatogr. 1979;185:375–392. doi:10.1016/S0021-9673(00)85615-0

Collinson MM. Recent trends in analytical applications of organically modified silicate materials. Trends Anal Chem. 2002;21(1):31–39. doi:10.1016/S0165-9936(01)00125-X

Jal PK, Patel S, Mishra BK. Chemical modification of silica surface by immobilization of functional groups for extractive concentration of metal ions. Talanta. 2004;62:1005–1028. doi:10.1016/j.talanta.2003.10.028

Wang Y, Tian M, Bi W, Row KH. Application of ionic liquids in high performance reversed-phase chromatography. Int J Mol Sci. 2009;10:2591–2610. doi:10.3390/ijms10062591

Pino V, Afonso AM. Surface-bonded ionic liquid stationary phases in high-performance liquid chromatography – a review. Anal Chim Acta. 2012;714:20–37. doi:10.1016/j.aca.2011.11.045

Vidal L, Riekkola ML, Canals A. Ionic liquid-modified materials for solid-phase extraction and separation: a review. Anal Chim Acta. 2012;715:19–41. doi:10.1016/j.aca.2011.11.050

Shamsi SA, Danielson ND. Utility of ionic liquids in analytical separations. J Sep Science. 2007;30:1729–1750. doi:10.1002/jssc.200700136

Bi W, Row KH. Comparison of different silica-based imidazolium stationary phases for LC in separation of alkaloids. Chromatographia. 2010;71:25–30. doi:10.1365/s10337-009-1380-9

Bi W, Zhou J, Row KH. Separation of xylose and glucose on different silica-confined ionic liquid stationary phases. Anal Chim Acta. 2010;677(2):162–168. doi:10.1016/j.aca.2010.08.004

Liu SJ, Zhou F, Xiao XH, Zhao L, Liu X, Jiang SX. Surface confined ionic liquid - A new stationary phase for the separation of ephedrines in high-performance liquid chromatography. Chin Chem Lett. 2004;15(9):1060–1062.

Qiu H, Jiang Q, Wei Z, Wang X, Liu X, Jiang S. Preparation and evaluation of a silica-based 1-alkyl-3-(propyl-3-sulfonate) imidazolium zwitterionic stationary phase for high-performance liquid chromatography. J Chromatogr A. 2007;1163(1–2):63–69. doi:10.1016/j.chroma.2007.06.001

Qiu H, Jiang S, Liu X. N-Methylimidazolium anion-exchange stationary phase for high-performance liquid chromatography. J Chromatogr A. 2006;1103(2):265–270. doi:10.1016/j.chroma.2005.11.035

Qiu H, Jiang S, Liu X, Zhao L. Novel imidazolium stationary phase for high-performance liquid chromatography. J Chromatogr A. 2006;1116(1–2):46–50. doi:10.1016/j.chroma.2006.03.016

Qiu H, Wang L, Liu X, Jiang S. Preparation and characterization of silica confined ionic liquids as chromatographic stationary phases through surface radical chain-transfer reaction. Analyst. 2009;134:460–465. doi:10.1039/B809125K

Liu K, Tolley HD, Lawson JS, Lee ML. Highly crosslinked polymeric monoliths with various C6 functional groups for reversed-phase capillary liquid chromatography of small molecules. J Chromatogr A. 2013;1321:80–87. doi:10.1016/j.chroma.2013.10.071

Lin H, Ou J, Zhang Z, Dong J, Zou H. Ring-opening polymerization reaction of polyhedral oligomeric silsesquioxanes (POSSs) for preparation of well-controlled 3D skeletal hybrid monoliths. Chem Commun. 2013;49(3):231–233. doi:10.1039/c2cc36881a

Iamamoto MS, Gushikem Y. Adsorption of metal ions from aqueous and ethanol solutions by silica gel functionalized with pyridinium ions. J Colloid Interface Sci. 1989;129(1):162–165. doi:10.1016/0021-9797(89)90426-8

Protsak IS, Kuzema PO, Tertykh VA, Bolbukh YM, Kozakevich RB. Thermogravimetric analysis of silicas chemically modified with products of deoligomerization of polydimethylsiloxane. J Therm Anal Calorim. 2015;121:547–557. doi:10.1007/s10973-015-4623-z

Sun M, Feng J, Wang X, Duan H, Li L, Luo C. Dicationic imidazolium ionic liquid modified silica as a novel reversed‐phase/anion‐exchange mixed‐mode stationary phase for high‐performance liquid chromatography. J Sep Sci. 2014;37(16):2153–2159. doi:10.1002/jssc.201400176

Haddad PR, Jackson PE. Ion Chromatography: Principles and Applications, Elsevier: Amsterdam; 1990. 775 p.

Konshin VV, Chuprynina DA, Lupanova IA, Konshina DzhN. Silica gel with covalently immobilized imidazolium salt as a new stationary phase for ion chromatography. AIP Conf Proc. 2020;2280(1):050028. doi:10.1063/5.0018424




DOI: https://doi.org/10.15826/chimtech.2021.8.4.09

Copyright (c) 2021 D.A. Chuprynina, I.A. Lupanova, V.V. Konshin, D.N. Konshina

Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 International License.

Scopus logo WorldCat logo DOAJ logo CAS logo BASE logo eLibrary logo

Chimica Techno Acta, 2014-2024
ISSN 2411-1414 (Online)
Copyright Notice