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Deoxydichlorination of aldehydes catalyzed by Diphenyl sulfoxide

I. A. Gorbunova, D. A. Shipilovskikh, S. A. Shipilovskikh

Abstract


The diphenyl sulfoxide-catalyzed conversion of aldehydes to 1,1-dichlorides is reported. The reaction proceeds via a sulfurous (IV)-catalysis manifold in which diphenyl sulfoxide turnover is achieved using oxalyl chloride as a consumable reagent.


Keywords


aldehydes; Lewis base catalysis; organocatalysis; diphenyl sulfoxide

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References


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DOI: https://doi.org/10.15826/chimtech.2021.8.4.08

Copyright (c) 2021 I.A. Gorbunova, D.A. Shipilovskikh, S.A. Shipilovskikh

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Chimica Techno Acta, 2014-2022
ISSN 2411-1414 (Online)