Cover Image

Obtaining cyclopentanone in the presence of metal oxides

I. V. Tsvetkova, A. A. Golovanov, A. A. Kondrateva, N. V. Chirkunova

Abstract


The possibility of obtaining cyclopentanone by pyrolysis of calcium adipate at different temperatures was considered. The pyrolysis proceeded with the formation of cyclopentanone and cyclopentene. The use of metal salts and metal oxide catalysts for the dehydrogenation of lower alkanes makes it possible to increase the yields of the target products. The best results were achieved in the presence of a «K-16u» catalyst.


Keywords


adipic acid, pyrolysis, cyclopentanone, cyclopentene, catalysts, metal oxides

Full Text:

PDF

References


Kisil IM, Preobrazhensky VA, Zolin VS, Gorodetskaya NI, Davydov YuI, Polikarpov AV, Salomykov VI. Method of utili-zation of acidic wastewater of caprolactam production: Pat. 2039740 Rus. Federation. 93009600/04; declared 02.24.1993; publ. 07.20.1995

Tsvetkova IV, Golovanov AA, Reznikova NS, Chirkunova NV. Obtaining cyclopentanone from acidic wastewater of capro-lactam production. Chimica Techno Acta. 2020;7(4):177–179. doi:10.15826/chimtech.2020.7.4.07

Sokolova AA, Glazko IL, Martynenko EA. Isolation of adipic acid from aqueous acid effluents of caprolactam production. Bulletin of MITHT of M.V. Lomonosov. 2013;6:78–71

Kogay TI, Vasileva NU. Synthesis, purification and identifi-cation of organic compounds: guidelines. Krasnoyarsk: Krasnoyarsk State University, 2005. 90p. Russian.

Kirpichnikov PA, Liakumovich AG, Pobedimskiy DG, Popova LM. Chemistry and technology of monomers for synthetic rubbers. Leningrad: Chimiya, 1981. 264 p. Russian.




DOI: https://doi.org/10.15826/chimtech.2021.8.4.10

Copyright (c) 2021 I.V. Tsvetkova, A.A. Golovanov, A.A. Kondrateva, N.V. Chirkunova

Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 International License.

Scopus logo WorldCat logo DOAJ logo CAS logo BASE logo eLibrary logo

Chimica Techno Acta, 2014-2024
ISSN 2411-1414 (Online)
Copyright Notice