![Cover Image](https://journals.urfu.ru/public/journals/6/cover_article_6670_en_US.jpg)
Testing conditions for CoMo HDS catalyst in the kinetic region: integrated approach using the math calculations and catalytic experiments
Abstract
Keywords
Full Text:
PDFReferences
Wang TE, Yang F, Song M, Han D. Recent advances in the unsupported catalysts for the hydrodesulfurization of fuel. Fuel Proc Technol.2022:235. doi:10.1016/j.fuproc.2022.107386
Ancheyta J. Modeling and simulation of catalytic reactors for petroleum refining. Model Simul Catal Reac Petroleum Refining. 2011. doi:10.1002/9780470933565.fmatter
Kaluža L, Gulková D, Šolcová O, Žilková N, Čejka J. Hy-drotreating catalysts supported on organized mesoporous alumina: Optimization of Mo deposition and promotional effects of Co and Ni. Appl Catal A Gen. 2008;351(1):93–101. doi:10.1016/j.apcata.2008.09.002
Huirache-Acuña R, Navarro Yerga RM, Pawelec B. Hy-drodesulfurization on Supported CoMoS2 Catalysts Ex Am-monium Tetrathiomolybdate: Effects of Support Morpholo-gy and Al Modification Method. Top Catal. 2022;65:1394–1407. doi:10.1007/s11244-022-01647-w
Iqrash Shafiq, Sumeer Shafique, Parveen Akhter, et al. Re-cent developments in alumina supported hydrodesulfuriza-tion catalysts for the production of sulfur-free refinery products: A technical review. Catal Rev. 2020;64:1–86. doi:10.1080/01614940.2020.1780824
Klimov OV, Vatutina YV, Nadeina KA. CoMoB/Al2O3 cata-lysts for hydrotreating of diesel fuel. The effect of the way of the boron addition to a support or an impregnating solu-tion. Catal Today. 2018;305:192–202. doi:10.1016/j.cattod.2017.07.004
Zhang C, Zhang Y, Zheng H. Improving both the activity and selectivity of CoMo/δ-Al2O3 by phosphorous modification for the hydrodesulfurization of fluid catalytic cracking naphtha. Energy Fuels. 2022;36(7):3825–3834. doi:10.1021/acs.energyfuels.1c04164
Chen Z, Liu Y, Chen J, Zhao Y, et al. Synthesis of alumina-nitrogen-doped carbon support for CoMo catalysts in hy-drodesulfurization process. Chin J Chem Engin. 2022;41:392–402. doi:10.1016/j.cjche.2021.09.015
Catita L, Quoineaud AA, Moreaud M, Espinat D, Pichon C, Delpoux O. Impact of citric acid on the impregnation of CoMoP/γ-Al2O3 catalysts: time and spatially resolved MRI and Raman imaging study. Top Catal. 2018;61(14):1474–1484. doi:10.1007/s11244-018-1038-7
Sun J, Mu C, Li Y, Zhao Y, Wang S, Ma X. The hydrotreat-ment of n-C16 over Pt/HPMo/SBA-15 and the investigation of diffusion effect using a novel W-P criterion. AIChE J. 2021;67(9):e17330. doi:10.1002/aic.17330
Chen A Cheng, Chen SL, Hua D run, et al. Diffusion of heavy oil in well-defined and uniform pore-structure cata-lyst under hydrodemetallization reaction conditions. Chem Eng J. 2013;231:420–426. doi:10.1016/j.cej.2013.07.035
Perego C, Peratello S. Experimental methods in catalytic kinetics. Catal Today. 1999;52(2–3):133–145. doi:10.1016/S0920-5861(99)00071-1
Dautzenberg FM. Ten guidelines for catalyst testing. ACS Symposium Ser. 1989:99–119. doi:10.1021/bk-1989-0411.ch011
Chen J, Yang H, Ring Z. Study of intra-particle diffusion effect on hydrodesulphurization of dibenzothiophenic com-pounds. Catal Today. 2005;109(1):93–98. doi:10.1016/j.cattod.2005.08.006
PA Ramachandran RC. Three-phase catalytic reactors. Gor-don Breach Sci Pub. 1983.
Marroquín G, Ancheyta J, Esteban C. A batch reactor study to determine effectiveness factors of commercial HDS cata-lyst. Catal Today. 2005;104(1):70–75. doi:10.1016/J.CATTOD.2005.03.026
Chen J, Mulgundmath V, Wang N. Accounting for vapor-liquid equilibrium in the modeling and simulation of a commercial hydrotreating reactor. Ind Eng Chem Res. 2011;50(3):1571–1579. doi:10.1021/ie101550g
Bhaskar M, Valavarasu G, Sairam B, Balaraman KS, Balu K. Three-phase reactor model to simulate the performance of pilot-plant and industrial trickle-bed reactors sustaining hydrotreating reactions. Ind Eng Chem Res. 2004;43(21):6654–6669. doi:10.1021/ie049642b
Palos R, Gutiérrez A, Hita I, et al. Kinetic modeling of hy-drotreating for enhanced upgrading of light cycle oil. Ind Eng Chem Res. 2019;58(29):13064–13075. doi:10.1021/acs.iecr.9b02095
Alvarez-Majmutov A, Chen J. Modeling and simulation of a multibed industrial hydrotreater with vapor-liquid equilib-rium. Ind Eng Chem Res. 2014;53(26):10566–10575. doi:10.1021/ie501032j
Mijatović IM, Glisic SB, Orlović AM. Modeling a catalytic reactor for hydrotreating of straight-run gas oil blended with fluid catalytic cracking naphtha and light cycle oil: in-fluence of vapor–liquid equilibrium. Ind Eng Chem Res. 2014;53(49):19104–19116. doi:10.1021/ie503188p
Jarullah AT, Mujtaba IM, Wood AS. Kinetic model develop-ment and simulation of simultaneous hydrodenitrogena-tion and hydrodemetallization of crude oil in trickle bed reactor. Fuel. 2011;90(6):2165–2181. doi:10.1016/j.fuel.2011.01.025
Macías MJ, Ancheyta J. Simulation of an isothermal hy-drodesulfurization small reactor with different catalyst particle shapes. Catal Today. 2004;98(1):243–252. doi:10.1016/j.cattod.2004.07.038
Mederos FS, Ancheyta J, Elizalde I. Dynamic modeling and simulation of hydrotreating of gas oil obtained from heavy crude oil. Appl Catal A Gen. 2012;425–426:13–27. doi:10.1016/j.apcata.2012.02.034
da Rocha Novaes L, de Resende NS, Salim VMM, Secchi AR. Modeling, simulation and kinetic parameter estimation for diesel hydrotreating. Fuel. 2017;209:184–193. doi:10.1016/j.fuel.2017.07.092
Korsten H, Hoffmann U. Three-phase reactor model for hydrotreating in pilot trickle-bed reactors. AIChE J. 1996;42(5):1350–1360. doi:10.1002/aic.690420515
Shokri S, Zarrinpashne S. A mathematical model for calcu-lation of effectiveness factor in catalyst pellets of hy-drotreating process. Pet Coal. 2006;48(1):27–33.
Nadeina KA, Danilevich VV, Kazakov MO. Silicon doping effect on the properties of the hydrotreating catalysts of FCC feedstock pretreatment. Appl Catal B Environ. 2021;280:119415. doi:10.1016/j.apcatb.2020.119415
Vatutina YV, Kazakov MO, Nadeina KA. Is it possible to reac-tivate hydrotreating catalyst poisoned by silicon? Catal To-day. 2021;378:43–56. doi:10.1016/j.cattod.2021.03.005
Fogler SH. Essentials of chemical reaction engineering: essenti chemica reactio engi. Pearson Education; 2010.
Mederos FS, Ancheyta J, Chen J. Review on criteria to en-sure ideal behaviors in trickle-bed reactors. Appl Catal A Gen. 2009;355(1):1–19. doi:10.1016/j.apcata.2008.11.018
Rodríguez MA, Ancheyta J. Modeling of hydrodesulfuriza-tion (HDS), hydrodenitrogenation (HDN), and the hydro-genation of aromatics (HDA) in a vacuum gas oil hy-drotreater. Energy Fuels. 2004;18(3):789–794. doi:10.1021/ef030172s
Felder R. Catalytic reactor design, by M. Orhan tarhan. McGraw‐Hill, 1983. В: Aiche J. 1984:372.
Mik IA, Klenov OP, Kazakov MO, Nadeina KA, Klimov O V, Noskov AS. Optimization of grading guard systems for trap-ping of particulates to prevent pressure drop buildup in gas oil hydrotreater. Fuel. 2021;285:119149. doi:10.1016/j.fuel.2020.119149
Ahmed T. Hydrocarbon Phase Behaviour . Gulf, Houston, TX. 1989:226.
Biardi G, Baldi G. Three-phase catalytic reactors. Catal To-day. 1999;52(2):223–234. doi:10.1016/S0920-5861(99)00077-2
Ancheyta J, Angeles MJ, Macías MJ, Marroquín G, Morales R. Changes in apparent reaction order and activation ener-gy in the hydrodesulfurization of real feedstocks. Energy Fuels. 2002;16(1):189–193. doi:10.1021/ef0101917
Ancheyta-Juárez J, Aguilar-Rodríguez E, Salazar-Sotelo D, Betancourt-Rivera G, Leiva-Nuncio M. Hydrotreating of straight run gas oil-light cycle oil blends. Appl Catal A Gen. 1999;180(1–2):195–205. doi:10.1016/S0926-860X(98)00351-2
Macías Hernández MJ, Morales RD, Ramírez-Lopez A. Simu-lation of the effectiveness factor for a tri-lobular catalyst on the hydrodesulfurization of diesel. 2009;7(1). doi:10.2202/1542-6580.1806
Duduković MP, Larachi F, Mills PL. Multiphase catalytic reactors: a perspective on current knowledge and future trends. Catal Rev. 2002;44(1):123–246. doi:10.1081/CR-120001460
Satterfield CN. Trickle-bed reactors. AlChE J. 1975;21(2):209–228.
Li C, Chen YW, Tsai MC. Highly restrictive diffusion under hydrotreating reactions of heavy residue oils. Ind Eng Chem Res. 1995;34(3):898–905. doi:10.1021/ie00042a024
Scamangas A, Papayannakos N, Marangozis J. Catalytic hy-drodesulfurization of a petroleum residue. Chem Eng Sci. 1982;37(12):1810–1812.
G. F. Froment, K.B. Bischoff J de W. Chemical reactor analy-sis and design. 1990.
Chang J, Liu J, Li D. Kinetics of resid hydrotreating reac-tions. Catal Today. 1998;43(3–4):233–239. doi:10.1016/S0920-5861(98)00152-7
Aris R. The Mathematical Theory of Diffusion and Reaction in Permeable Catalysts: The theory of the steady state. Ox-ford Uni.; 1975.
Carberry JJ. Chemical and Catalytic Reaction Engineering. Courier Corporation; 2001.
Thommes M, Kaneko K, Neimark A V., et al. Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report). Pure Appl Chem. 2015;87(9–10):1051–1069. doi:10.1515/pac-2014-1117
Wang HW, Skeldon P, Thompson GE. XPS studies of MoS2 formation from ammonium tetrathiomolybdate solutions. Surf Coatings Technol. 1997;91:200–207. doi:10.1016/S0257-8972(96)03186-6
Gandubert AD, Legens C, Guillaume D, Payen E. X-ray pho-toelectron spectroscopy surface quantification of sulfided CoMoP catalysts – relation between activity and promoted sites – Part I: influence of the Co/Mo Ratio. Surf Interface Anal. 2006;38:206–209. doi:10.1002/sia.2249
Vatutina Y V, Klimov O V, Stolyarova EA, et al. Influence of the phosphorus addition ways on properties of CoMo-catalysts of hydrotreating. Catal Today. 2019;329:13–23. doi:10.1016/j.cattod.2019.01.005
Pecoraro T.A., Chianelli R.R. Hydrodesulfurization catalysis by transition metal sulfides. J Catal. 1981;67:430. doi:10.1016/0021-9517(81)90303-1
DOI: https://doi.org/10.15826/chimtech.2023.10.2.08
Copyright (c) 2023 Polina P. Mukhacheva, Yuliya V. Vatutina, Ivan A. Mik, Ksenia A. Nadeina, Maxim O. Kazakov, Oleg P. Klenov, Oleg V. Klimov, Aleksandr S. Noskov
![Creative Commons License](http://licensebuttons.net/l/by/4.0/88x31.png)
This work is licensed under a Creative Commons Attribution 4.0 International License.
Chimica Techno Acta, 2014-2024
ISSN 2411-1414 (Online)
Copyright Notice