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Substutited molybdates of bismuth on a basis of Bi13Mo5O34±δ: production and properties

Z. A. Mikhailovskaya, E. S. Buyanova, S. A. Petrova, R. G. Zakharov


The present work is devoted to the investigation of the methods of a synthesis and properties of the one of the most interesting one-dimensional oxygen –ion conductors, the Bi13Mo5O34±δ –based complex oxides. The general compositions of these bismuth molybdates are Bi13Mo5-хMeхO34-δ, and Bi13-yMeyMo5O34-δ, with Me = Mg, Ca, Sr, Ba (IIA group) and Co, Fe, Ni (Fe triade). The samples have been synthesized using conventional ceramic technology. The powders and pellets of the bismuth molybdates were studied by X-Ray diffraction, scanning electron microscopy, laser dispersion, dilatometry, atom absorption and inductively-coupled plasma atomic emission spectrometry. Electrical conductivity has been studied using impedance spectroscopy method.


bismuth molybdates; oxygen-ionic conductivity; ion transport; x-ray diffraction; electron microscopy


Boivin JC. Structural and electrochemical features of fast oxide ion conductors. Int J Inorg Mater. 2001;3(8):1261-66. doi:10.1016/S1466-6049(01)00118-0

Abraham F, Boivin JC, Mairesse G, Nowogrocki G. BIMEVOX series. A new family of high performances oxide ion conductors. Solid State Ionics. 1990;40-1(2):934-7. doi:10.1016/0167-2738(90)90157M

Fonseca FC, Steil MC, Vannier RN, Mairesse G, Muccillo R. Grain-sized influence on the phase transition of Bi26Mo9WO69: An X-ray diffraction and impedance spectroscopy study. Solid State Ionics. 2001;140(1-2):161-71. doi:10.1016/S0167-2738(01)00705-6

Enjalbert R, Hasselmann G, Galy J. [Bi12O14E12]nColumns and Lone Pairs E in Bi13Mo4VO34E13: Synthesis, Crystal Structure, and Chemistry of the Bi2O3-MoO3-V2O5 System. J Solid State Chem. 1997;131(2):236-45. doi:10.1006/jssc.1997.7367

Vannier RN, Mairesse G, Abraham F, Nowogrocki G. Bi26Mo10Oδ solid solution type in the Bi2O3-MoO3-V2O5 ternary diagram. J Solid State Chem. 1996;122(2):394-406. doi:10.1006/jssc.1996.0133

Vannier RN, Danzé S, Nowogrocki G, Huvé M, Mairesse G. New class of mono-dimensional bismuth-based oxide anion conductors with a structure based on [Bi12O14] columns. Solid State Ionics. 2000;136-7:51-9. doi:10.1016/s0167/2738(00)00351-9

Rodriguez-Carvajal Ju. Recent advances in magnetic structure determination by neutron powder diffraction. Physica B. 1993;192(1-2):55-69. doi:10.1016/0921-4526(93)90108-I

Irvine JTS, Sinclair DC, West AR. Electroceramics: Characterization by impedance spectroscopy. Adv Mater. 1990;2(3):132-8. doi:10.1002/adma.19900020304


Copyright (c) 2014 Z. A. Mikhailovskaya, E. S. Buyanova, S. A. Petrova, R. G. Zakharov

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Chimica Techno Acta, 2014-2024
ISSN 2411-1414 (Online)
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