High purity β-Bi 2 O 3  preparation by thermal decomposition of tartrates

Evgeniya V. Timakova; Tatiana E. Timakova; Liubov I. Afonina

doi:10.15826/chimtech.2023.10.3.04

High purity β-Bi₂O₃ preparation by thermal decomposition of tartrates

Evgeniya V. Timakova, Tatiana E. Timakova, Liubov I. Afonina

Abstract

The processes of oxidative thermolysis of bismuth(III) DL-tartrate BiC₄H₃O₆ obtained by the interaction of high-purity basic bismuth(III) nitrates [Bi₆O₄(OH)₄](NO₃)₆·H₂O and [Bi₆O₅(OH)₃](NO₃)₅·3H₂O with DL-tartaric acid solution have been investigated. The products of precipitation have been studied by methods of X-ray diffraction and thermal analysis, IR and Raman spectroscopy and chemical analysis. The staging of thermal transformation processes has been determined. Morphological studies and grain size analysis of initial precursors and final products of their thermal transformations have been carried out. The possibility of obtaining fine crystalline powders of tetragonal bismuth(III) oxide modification β-Bi₂O₃ by oxidative thermolysis of DL-BiC₄H₃O₆ has been shown.

Keywords

basic bismuth(III) nitrate; DL-tartaric acid; X-ray diffraction; thermal transformations; β-bismuth(III) oxide; fine-crystal powders

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References

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DOI: https://doi.org/10.15826/chimtech.2023.10.3.04

Copyright (c) 2023 Evgeniya V. Timakova, Tatiana E. Timakova, Liubov I. Afonina