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Fast-activating reserve power sources: is lead dead indeed?

Pavel A. Shcheglov, Dmitry A. Samsonov, Anatoly B. Pavlenkov, Tatiana L. Kulova, Alexey Yu. Rychagov, Alexander M. Skundin, Evgeniya Yu. Postnova

Abstract


The purpose of this research is to improve the performance and reduce the activation time of reserve power sources based on lead-acid systems at lower temperatures, down to –50 °C. Physico-chemical factors affecting the activation speed of reserve power sources based on Pb–HClO4–PbO2 and Zn–HClO4–PbO2 systems are investigated using chronopotentiometry, scanning electron microscopy, and standard contact porosimetry. Two approaches to the improvement of the low-temperature performance of power sources are used. The first one is based on the substitution of lead as anodic material with zinc. This allows the increase in discharge voltage and simultaneous decrease in activation time, but brings about the instability of discharge characteristics and, finally, deteriorates the reliability of power sources. The second approach is based on the use of PbO2 cathode material with enhanced nanoporosity. The chronopotentiometric method in galvanostatic mode is applied to the quality estimation of cathodes. The criterion of applicability of cathodes for reserve power sources consists in the low discharge overvoltage (0.1–0.2 V). Efficient performance of reserve power sources possessing the stable discharge voltage (1.5–1.8 V per cell) and the unprecedentedly short activation time (under 30 ms) even at lower temperatures (down to –50 °C) is achieved. The results are verified by fabrication and testing of pilot batches of miniaturized reserve power sources having microcells’ volume of 0.02 ml. The second approach to the improvement of power sources is transferred into the industrial production.

Keywords


reserve power source; activation time; discharge; lead dioxide; lead; zinc

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References


Beard KW, Reddy TB, editors. Linden’s Handbook of Batter-ies. 5th ed. New York, Chicago, etc.: McGraw Hill; 2019. 1456 p.

Bagotsky VS, Skundin AM, Volfkovich YuM. Electrochemical power sources: Batteries, Fuel Cells, and Supercapacitors. Hoboken NJ: John Wiley & Sons; 2015. 403 p. doi:10.1002/9781118942857

Ritchie AG. Military applications of reserve batteries. Philos Trans Royal Soc A. 1996;354(1712):1643–1652. doi:10.1098/rsta.1996.0070

Clesca O. Tailoring the size and performance of a reserve lithium battery for the next generation fuzes. In: 56th Na-tional Defense Industrial Association Annual Fuze Confer-ence ‘Next Generation Fuzing for Next Generation Weap-ons’; 2012 May 14–16; Baltimore MD, USA. 13708.

Straver J, inventor; Thales Nederland BV, assignee. Reserve batterij en de toepassingsmogelijkheden ervan. The Neth-erlands patent NL 1022034. 2004 Aug 02. Dutch.

Hein R. State of the art fuze batteries and their perfor-mance. In: 61th National Defense Industrial Association Annual Fuze Conference ‘Fuzing Solutions – A Global Per-spective’; 2018 May 15–17; San Diego CA, USA. 20455.

Hein R, inventor. Diehl & Eagle Picher GmbH, assignee. Aktivierungseinrichtung für eine Batterie für einen el-ektronischen Zündmechanismus. Germany patent DE 102019004140. 2020 Dec 17. German.

Schisselbauer P, Wightman B. Lithium battery innovations for projectile munitions. In: 62th National Defense Indus-trial Association Annual Fuze Conference ‘Fuzing Innova-tions for Tommorrow’s Weapons’; 2019 May 13–15; Buffalo NY, USA. 21767.

Jeon KY, Yang IC, Park SH, Kim KH, inventors; Vitzrocell Co Ltd, assignee. Ampoule type reserve battery. South Korea patent KR 10-1293523. 2013 Aug 02. Korean.

Jeon KY, Yang IC, Kim KH, inventors; Vitzrocell Co Ltd, as-signee. Reserve battery with improved prevention of insu-lation failure of positive terminal. South Korea patent KR 10-1818913. 2016 Sep 06. Korean.

Golembiovskii VS, Esiev RU, Kolpashchikov YuV, Pavlenkov AB, Chizhevskii OT, inventors; JSC ‘Scientific and Produc-tion Association ‘Pribor’, assignee. Energosoderzhashchii istochnik toka. The Russian Federation patent RU 2487313. 2012 Feb 03. Russian.

Shpekina VI. Development of the lead dioxide electrodepo-sition technology onto various substrates under ultrasonic field [dissertation]. Saratov (Russia): The Saratov state technical university; 2016. 136 p. Russian.

Brickwedde LH. Properties of aqueous solutions of perchlo-ric acid. J Res Nat Bur Stand. 1949;42:309–329. doi:10.6028/JRES.042.026

Yoon SH, Son JT, Oh JS. Miniaturized g- and spin-activated Pb/HBF4/PbO2 reserve batteries as power sources for elec-tronic fuzes. J Power Sources. 2006;162(2):1421–1430. doi:10.1016/j.jpowsour.2006.07.051

Wich H. Lead is dead. In: 58th National Defense Industrial Association Annual Fuze Conference ‘Fuzing in a Challeng-ing Environment’; 2015 Jul 7–9; Baltimore MD, USA. 17701.

Korotkov VA, Shpekina VI, Solovyova ND. The influence of ultrasound on nucleation in electrodeposition of lead diox-ide on a nickel substrate. Electrochem Energetics. 2021;21(2):108–113. Russian. doi:10.18500/1608-4039-2021-21-2-108-113

Shpekina VI, Korotkov VA, Solovyova ND. Electrodeposition of lead dioxide on titanium substrate. Electrochem Ener-getics. 2021;21(4):191–196. Russian. doi:10.18500/1608-4039-2021-21-4-191-196

Shpekina VI, Korotkov VA, Solovyova ND. The effect of ul-trasound on the coating properties and the kinetics of lead dioxide electrodeposition on the steel base. Electrochem Energetics. 2022;22(3):139–146. Russian. doi:10.18500/1608-4039-2022-22-3-139-146

Gorbachev NV, Gorbacheva EYu, Solovyova ND, Krasnov VV. The anodic behavior of electrodeposited lead and zinc in perchloric acid solution and the possibility of their use as anodes in reserve power sources. Electrochem Energetics. 2011;11(3):154–157. Russian. doi:10.18500/1608-4039-2011-11-3-154-157

Gorbachev NV. Technology of formation of anodic layers of electrodes of reserve power sources with perchloric acid [dissertation]. Saratov (Russia): The Saratov state tech-nical university; 2011. 127 p. Russian.

GOST 9.305-84. Unified system of corrosion and ageing protection. Metal and non-metal inorganic coatings. Tech-nological process operations for coating production [inter-state standard]. Moscow (Russia): Izdatel’stvo standartov; 2003. 107 p. Russian.

GOST 9.302–88. Unified system of corrosion and ageing protection. Metal and non-metal in organic coatings. Con-trol methods [interstate standard]. Moscow (Russia): Izda-tel’stvo standartov; 2001. 38 p. Russian.

Volfkovich YuM, Bagotzky VS. The method of standard po-rosimetry: 1. Principles and possibilities. J Power Sources. 1994;48(3):327–338. doi:10.1016/0378-7753(94)80029-4

Volfkovich YuM, Bagotzky VS, Sosenkin VE, Blinov IA. The standard contact porosimetry. Colloids Surf A: Physicochem Eng Asp. 2001;187–188:349–365. doi:10.1016/S0927-7757(01)00650-1

Vol’fkovich YM, Sakars AV, Volinsky AA. Application of the standard porosimetry method for nanomaterials. Int J Nan-otechnol. 2005;2(2):292–302. doi:10.1504/IJNT.2005.008066

Sukhotin AM, editor. Spravochnik po elektrokhimii [Hand-book of Electrochemistry]. Leningrad: Khimiya; 1981. 488 p. Russian.

GOST R 58593–2019. Primary and secondary cells and bat-teries. Vocabulary [national standard of the Russian Feder-ation]. Moscow (Russia): Standartinform; 2019. 66 p. Rus-sian.

Prosyanyuk VV, Suvorov LS, Prudnikov NV. Direct chemical energy conversion of power-condensed systems into elec-tric energy in combustion mode. Rossiiskiy Khimicheskiy Zhurnal. 2021;65(3):67–71. Russian. doi:10.6060/rcj.2021653.9

Prosyanyuk VV, Suvorov LS, Prudnikov NV, Gilbert SV, Zyuzina DS. On the possibility of expansion of the domestic component base of current sources based on energy con-densed systems. Rossiiskiy Khimicheskiy Zhurnal. 2020;64(3):82–87. Russian. doi:10.6060/rcj.2020643.10

Vetter KJ. Elektrochemische Kinetik. Berlin, Heidelberg: Springer; 1961. 699 S. German. doi:10.1007/978-3-642-86547-3

Li X, Pletcher D, Walsh FC. Electrodeposited lead dioxide coatings. Chem Soc Rev. 2011;40(7):3879–3894. doi:10.1039/c0cs00213e

Kong J, Shi S, Kong L, Zhu X, Ni J. Preparation and charac-terization of PbO2 electrodes doped with different rare earth oxides. Electrochim Acta. 2007;53(4):2048–2054. doi:10.1016/j.electacta.2007.09.003

Velichenko AB, Amadelli R, Baranova EA, Girenko DV, Danilov FI. Electrodeposition of Co-doped lead dioxide and its physicochemical properties. J Electroanal Chem. 2002;527(1–2):56–64. doi:10.1016/S0022-0728(02)00828-8

Xu H, Yuan Q, Shao D, Yang H, Liang J, Feng J, Yan W. Fab-rication and characterization of PbO2 electrode modified with [Fe(CN)6]3− and its application on electrochemical degradation of alkali lignin. J Hazard Mater. 2015;286:509–516. doi:10.1016/j.jhazmat.2014.12.065

Shcheglov PA, Samsonov DA, Pavlenkov AB, Kulova TL, Ry-chagov AYu, Nikolskaya NF, Shiryaev AA, Skundin AM. The effect of the positive electrode properties on the activation time of the lead–perchloric acid–lead dioxide-based reserve chemical power sources. Russ J Electrochem. 2023;59(12):1062–1070. doi:10.1134/S1023193523120121

Shcheglov PA, Samsonov DA, Pavlenkov AB, Kulova TL, Ry-chagov AYu, Andreev VN, Skundin AM. Investigation of physicochemical characteristics of lead dioxide coatings to enhance the performance of reserve quickly activated chemical power sources in the lead–perchloric acid–lead dioxide system. Russ J Phys Chem A. 2023;97(12):2835–2844. doi:10.1134/S0036024423120269

Pavlov D. Lead-Acid Batteries: Science and Technology: A Handbook of Lead-Acid Battery Technology and Its Influ-ence on the Product. 2nd ed. Amsterdam: Elsevier; 2017. 720 p.

Pavlov D, Balkanov I, Halachev T, Rachev P. Hydration and amorphization of active mass PbO2 particles and their in-fluence on the electrical properties of the lead-acid battery positive plate. J Electrochem Soc. 1989;136(11):3189–3197. doi:10.1149/1.2096424

Pavlov D. The lead-acid battery lead dioxide active mass: A gel–crystal system with proton and electron conductivity. J Electrochem Soc. 1992;139(11):3075–3079. doi:10.1149/1.2069034

Pavlov D. Influence of crystal and gel zones on the capacity of the lead dioxide active mass. J Power Sources. 1992;40(1–2):169–173. doi:10.1016/0378-7753(92)80049-H

Pavlov D, Petkova G, Dimitrov M, Shiomi M, Tsubota M. Influence of fast charge on the life cycle of positive lead-acid battery plates. J Power Sources. 2000;87(1–2):39–56. doi:10.1016/S0378-7753(99)00358-4

Dodson VH. The composition and performance of positive plate material in the lead-acid battery. J Electrochem Soc. 1961;108(5):406–412. doi:10.1149/1.2428101

Rüetschi P. Influence of crystal structure and interparticle contact on the capacity of PbO2 electrodes. J Electrochem Soc. 1992;139(5):1347–1351. doi:10.1149/1.2069410

Petersson I, Berghult B, Ahlberg E. Thin lead dioxide elec-trodes for high current density applications in semi-bipolar batteries. J Power Sources. 1998;74(1):68–76. doi:10.1016/S0378-7753(98)00035-4

Qu D. Fundamental principles of battery design: Porous electrodes. AIP Conf Proc. 2014;1597:14–25. doi:10.1063/1.4878477

Shcheglov PA, Samsonov DA, Pavlenkov AB, Sidorov YuM, Samoryadov AV. Application of innovative polymer compo-site materials based on polyphenylene sulfide in the design of power supply devices. Plasticheskie massy. 2023;(3–4):39–43. Russian. doi:10.35164/0554-2901-2023-3-4-39-43




DOI: https://doi.org/10.15826/chimtech.2024.11.1.03

Copyright (c) 2023 Pavel A. Shcheglov, Dmitry A. Samsonov, Anatoly B. Pavlenkov, Tatiana L. Kulova, Alexey Yu. Rychagov, Alexander M. Skundin, Evgeniya Yu. Postnova

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Chimica Techno Acta, 2014-2024
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