ОПРЕДЕЛЕНИЕ МИКРОЭЛЕМЕНТОВ В РАСТЕНИЯХ МЕТОДОМ ДУГОВОЙ АТОМНО-ЭМИССИОННОЙ СПЕКТРОМЕТРИИ
Аннотация
Растения связывают воедино атмосферу, биосферу и гидросферу, участвуют в миграции химических элементов и указывают на антропогенное загрязнение окружающей среды. Поэтому определение в растениях содержаний широкого круга эссенциальных и токсичных элементов имеет важное значение. Разработана экспрессная методика определения 23 микроэлементов в порошках растительных материалов (без озоления и кислотного разложения) методом атомно-эмиссионной спектрометрии с дуговым разрядом (АЭС-ДР). Применение специальных приемов получения и обработки спектральной информации обеспечило повышение точности результатов анализа в диапазонах n ∙(10-6-10-4) до 10 % мас. Правильность результатов подтверждена контролем по зашифрованным стандартным образцам состава растений и сравнением с данными, полученными по аттестованным методикам атомно-эмиссионной и масс-спектрометрии с индуктивно связанной плазмой. Методика АЭС-ДР применима для определения элементов в растениях с экологически чистых и загрязненных территорий, различных по ландшафту; обеспечивает получение новых аналитических данных, которые подтверждены прослеживаемостью к известным международным стандартным образцам состава растений.
Ключевые слова: растения, микроэлементы, атомно-эмиссионная спектрометрия с дуговым разрядом, прослеживаемость результатов
DOI: http://dx.doi.org/10.15826/analitika.2019.23.3.011Полный текст:
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