РАЗВИТИЕ РЕНТГЕНОСПЕКТРАЛЬНОГО АНАЛИЗА В Г. НОВОСИБИРСКЕ (Электронно-зондовый микроанализ и рентгенофлуоресцентный анализ с использованием синхротронного излучения)
Аннотация
Рассмотрен вклад Новосибирских рентгенофизиков в становление и развитие двух направлений рентгеноспектрального анализа: электронно-зондового микроанализа и рентгенофлуоресцентного анализа с использованием синхротронного излучения. Исследования по геологической тематике в Институте геологии и геофизики СО АН СССР с применением электронно-зондового микроанализатора MS-46 французской фирмы CAMECA (с 1967 г.) послужили основой разработки методик количественного рентгеновского микроанализа породообразующих минералов, так как методы количественных определений содержаний элементов с малыми атомными номерами в длинноволновой рентгеновской области ещё только зарождались. По мере развития и совершенствования технической базы метода (микрозонды JXA-5A, JEOL, 1975; Камебакс Микро, CAMECA, 1981; JXA-8100, JEOL, 2003; JXA-8230, JEOL, 2016; электронно-вычислительная техника) непрерывно изменялось программное обеспечение по управлению работой приборов и переводу измеренных интенсивностей аналитических линий в содержания элементов. Первые результаты элементного анализа, полученные с использованием синхротронного излучения для возбуждения рентгеновской флуоресценции (РФА-СИ) на ускорительном кольце ВЭПП-3 в Институте ядерной физики СО АН СССР, опубликованы в 1977 г. В последующие годы на станции элементного РФА-СИ проводились исследования образцов различной природы — биологических (биоткани сердца, печени и лёгких, волосы, кости, растения), геологических, объектов окружающей среды (почвы, отложения, аэрозоли и др.), археологических объектов, а также новых технологических материалов. Разработаны методики определения химических элементов в образцах малой массы (миллиграммы), в частности, в уникальных образцах образцов лунного грунта, биопсийного материала тканей миокарда человека и др. Сканирующее устройство на станции элементного РФА-СИ обеспечило возможность получения информации для реконструкции изменения климата за разные периоды времени — от 100 до 1000 лет. На станции развивается новый неразрушающий метод конфокальной рентгеновской микроскопии для исследования микрообъектов и визуализации распределения химических элементов в протяжённых объектах.
Ключевые слова: электронно-зондовый микроанализ, рентгенофлуоресцентный анализ, синхротронное излучение
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REFERENCE
Shcherbakov R.N. V.K. [Roentgen is the genius of simplicity and precision of the experiment]. Priroda [Nature], 2020, no. 2 (1254), pp. 54-66 (in Russian).
Revenko A.G. [125 years since the discovery of X-rays].
Analitika i control` [Analytics and control], 2020, vol. 24, no. 1,
pp. 66–79 (in Russian). DOI: 10.15826/analitika.2020.24.1.008
Kalinin B.D. [X-ray radiation research and the development of X-ray engineering in St. Petersburg]. Analitika i kontrol [Analytics and control], 2020, vol. 24, no. 3, pp. 201–229 (in Russian). DOI: 10.15826/analitika.2020.24.3.005
Berkhoer I.D., Komyak N.I., Mezhevich A.N., Sorin M.I. X-ray spectral analysis in the cement industry of the USSR. 1974. M. (Dopolnitel'nye doklady /VI Mezhdunarodny` kongress po khimii tsementa; Razdel 1) [(Suppl. report / VI Intern. Congress on the chemistry of cement], Sect. 1. 1-5. 169), 10 p. (in Russian)
Blank A.B., Eksperiandova L.P. Specimen preparation in x-ray fluorescence analysis of materials and natural objects. X-Ray Spectrom., 1998, vol. 27, no. 3, pp. 147–160. Doi:10.1002/(SICI)1097-4539(199805/06)27:3<147::AID-XRS263>3.0. CO;2-P
Karmanov V.I., Pokhodnya I.K. [X-ray spectral analysis with one standard and intensity correction on a computer]. Zavodskaia laboratoriia [Industrial laboratory], 1972, vol. 38, no. 2, pp. 167-169 (in Russian).
Karmanov V.I., Voitkevich V.G., Trikoz V.P., Pokhodnya I.K. [X-ray spectral analysis of welding slag]. Zhurn. Analyt. Chem. [Journal of Analytical Chemistry], 1979, vol. 34, no. 7, pp. 1329-1334 (in Russian).
Kochmola N.M., Bondarenko V.P. [Influence of the particle size of ores and their mixtures on the results of determination of calcium by the X-ray fluorescence method]. Zhurn. Analyt. Chem. [Journal of Analytical Chemistry], 1987, vol. 42, no. 7, pp. 1216-1220 (in Russian).
Zagorodny V.V., Karmanov V.I., Gordeeva G.L. [X-ray fluorescence analysis of manganese agglomerates]. Zhurn. Analyt. Chem. [Journal of Analytical Chemistry], 1984, vol. 39, no. 3, pp. 498-503 (in Russian).
Makarovskaya Ya.N., Eksperiandova L.P., Blank A.B. Sampling of Natural Water Using the Ultrasonic and Ultraviolet Decomposition of Humic Substances. Journal of Analytical Chemistry, 2003, vol. 58, no. 2, pp. 110-113. Doi: 10.1023/A:1022341601795
Pivovarov A.V., Weinstein E.E. [On one method for eliminating focusing errors and increasing the luminosity of an X-ray spectrograph of the Cauchois type]. Zhurn. Analyt. Chem. [Journal of Analytical Chemistry], 1951, vol. 6, no. 6, pp. 386-387 (in Russian).
Ilyukevich Yu.A., Demyanikov I.G., Gladyshev V.P. [On the method of increasing the accuracy of X-ray fluorescence analysis of powder samples of the products of concentration of non-ferrous metal ores]. Zhurn. Analyt. Chem. [Journal of Analytical Chemistry], 1978, vol. 33, no. 7, pp. 1427-1429 (in Russian).
Mamaev V.E., Yuzvak L.A. [X-ray spectral determination of tantalum by fusion of the analyzed samples with a borax]. Apparatura i metody rentgenovskogo analiza [Equipment and methods of X-ray analysis], L.: SKBRA, 1969, Issue 4, pp. 176-179 (in Russian).
Paramonov F.P. [Determination of the concentration of elements by the selection of a theoretical standard]. Izvestiia Akademii Nauk Kazakhskoi SSR. Seriia Khimiia [Bulletin of the Academy of Sciences of the Kazakh SSR. Seria chemistry], 1966, no. 3, pp. 97-98 (in Russian).
Favinsky I.Ya. [Compensation of the effect of unsaturation in X-ray spectral fluorescence analysis using scattered radiation]. Apparatura i metody rentgenovskogo analiza [Equipment and methods of X-ray analysis], L.: Mashinostroenie Publ., 1972, Issue 10, pp. 143-147 (in Russian).
Favinsky I.Ya., Pan’kov S.D., Smagunova A.N., Losev N.F. [Evaluation and accounting of the effect of particle size and chemical composition of batch samples during X-ray spectral analysis]. Apparatura i metody rentgenovskogo analiza [Equipment and methods of X-ray analysis], L., Mashinostroenie Publ., 1977, Issue 19, pp. 32-36 (in Russian).
Stulov B.A. [Application of the standard-background method for X-ray spectral fluorescence analysis of pulps]. Zavodskaia laboratoriia [Industrial laboratory], 1967, vol. 33, no. 12, pp. 1505-1507 (in Russian).
Rudnevsky N.K., Mashin N.I. [X-ray spectral determination of the thickness of copper-nickel films on a sitall substrate using one-component standards. Zavodskaia laboratoriia [Industrial laboratory], 1984, vol. 50, no. 9, pp. 22-24 (in Russian).
Rehkolainen G.I. [Study of scattered X-ray radiation in the region of the L-fluorescence spectrum of rare-earth elements]. Apparatura i metody rentgenovskogo analiza [Equipment and methods of X-ray analysis], L., Mashinostroenie Publ., 1972, Issue 11, pp. 89-94 (in Russian).
Rehkolainen G.I., Gul’neva N.F. [X-ray fluorescence analysis of plant materials using incoherently scattered radiation]. Apparatura i metody rentgenovskogo analiza [Equipment and methods of X-ray analysis], L., Mashinostroenie Publ., 1986, Issue 35, pp. 91-96 (in Russian).
Bondarenko G.V., Dolgareva A.P. [X-ray spectral analysis of thin magnetic films using a SPARK-1 spectrometer]. Apparatura i metody rentgenovskogo analiza [Equipment and methods of X-ray analysis], L., Mashinostroenie Publ., 1983, Issue 31, pp. 128-132 (in Russian).
Konev A.V., Grigoriev E.V., Sukhovolskaya N.E., Astakhova N.A., Rubtsova S.N. [Physical criterion of background quality as a comparison standard in X-ray spectral analysis]. Zhurn. Analyt. Chem. [Journal of Analytical Chemistry], 1984, vol. 39, no. 2, pp. 197-203 (in Russian).
Konev A.V., Sukhovolskaya N.E., Smagunova A.N., Grigoriev E.V., Astakhova N.A. [Taking into account the unsaturation of the emitter in X-ray spectral analysis]. Zhurn. Analyt. Chem. [Journal of Analytical Chemistry], 1984, vol. 39, no. 3, pp. 405-410 (in Russian).
Verkhovodov P.A., Molodetskaya I.E., Konev A.V. [X-ray fluorescence determination of noble and non-ferrous metals in technological products]. Zhurn. Analyt. Chem. [Journal of Analytical Chemistry], 1975, vol. 30, no. 3, pp. 472-478 (in Russian).
Shestakov V.A., Arkhipov N.A., Makarov D.F., Kukushkin Yu.N. [X-ray spectral analysis of sludge and platinum concentrates for precious metals]. Zhurn. Analyt. Chem. [Journal of Analytical Chemistry], 1974, vol. 29, no. 1, pp. 2176-2180 (in Russian).
Bondarenko B.Yu. [A method for prompt diagnosis of systematic errors in X-ray spectral fluorescence analysis]. Zavodskaia laboratoriia [Industrial laboratory], 1990, vol. 56, no. 7, pp. 96-102 (in Russian).
Borkhodoev V.Ya. [Determination of the background in the channels of an X-ray fluorescence quantometer in the analysis of rocks for the main components]. Zhurn. Analyt. Chem. [Journal of Analytical Chemistry], 1987, vol. 42, no. 2, pp. 241-245 (in Russian).
Borkhodoev V.Ya. Rentgenofluorestsentnyi analiz gornykh porod sposobom fundamental'nykh parametrov [X-ray fluorescence analysis of rocks by fundamental parameter method]. NEISRI FEB RAS, Magadan. 1999, pp. 279 (in Russian).
Pyatkov A.G., Eliseenko L.G., Romanenko I.M., Kozodoy G.I. [The method of successive approximations with semiempirical coefficients for X-ray spectral analysis of geological samples]. Apparatura i metody rentgenovskogo analiza [Equipment and methods of X-ray analysis], L., Mashinostroenie Publ., 1975, Issue 16, pp. 56-61 (in Russian).
Ivanenko V.V., Kustov V.N., Metelev A.Yu., Rakita K.A. [X-ray Radiometric Determination of Cobalt in Ferromanganese Nodules in the Ocean]. Zhurn. Analyt. Chem. [Journal of Analytical Chemistry], 1989, vol. 44, no. 2, pp. 351-355.
Ivanenko V.V., Kustov V.N., Metelev A.Yu., Grigoriev A.I. [Development of methods of nuclear physical analysis (NPA) of the elemental composition of matter at the Institute of Chemistry of the Far Eastern Branch of the RAS]. Vestnik dal’nevostochnogo Otdeleniia Rossiyskoi Akademii Nauk [Bulletin of the Far Eastern Branch of the Russian Academy of Sciences], 2002, no. 4, pp. 3-20 (in Russian).
Losev N.F., Smagunova A.N., Pavlinsky G.V., Afonin V.P., Gunicheva T.N., Revenko A.G. [Modern methods of X-ray spectral fluorescence analysis]. Zavodskaia laboratoriia [Industrial laboratory], 1968, vol. 34, no. 8, pp. 944-960 (in Russian).
Losev N.F., Smagunova A.N., Revenko A.G., Pavlinsky G.V., Tarasenko S.A., Rozova O.F., Velichko Yu.I. [The current state of X-ray spectral analysis]. Zavodskaia laboratoriia [Industrial laboratory], 1977, vol. 43, no.№ 2, pp. 160-178 (in Russian).
Domashevskaya E.P., Shulakov A.S., Sukhorukov V.L., Amusya M.Ya., Brytov I.A., Vinogradov A.V., Ivanova T.M., Narbutt K.I., Nefedov V.I., Kurmaev E.Z., Trapeznikov V.A., Teterin Yu.A., Shuvaev A.T. Nauchnye shkoly rentgenovskoi i rentgenoelektronnoi spektroskopii Rossii [Scientific schools of X-ray and X-ray electron spectroscopy in Russia]. / Ed. E.P. Domashevskaya. Voronezh: Voronezh State University Publishing House, 2015, 330 pp. (in Russian)
Ostroumov G.V., Lyubimova L.N., Malyshev V.I., Sidorenko G.A., Yakubovich A.L. Laboratory Service at the Fedorovskii All-Russia Institute of Mineral Resources. Journal of Analytical Chemistry, 2002, vol. 57, no. 8, pp. 739-747. Doi: 10.1023/A:1016886228542
Nikolai Fomich Losev [Nikolai Fomich Losev]. Irkutsk: Publishing House “Imprint”. 2003. 56 p. (in Russian).
Petrov L.L., Vasilieva I.E., Gunicheva T.N., Kuznetsova A.I., Men’shikov V.I., Pavlova L.A., Prokopchuk S.I., Smirnova E.V., Finkelshtein A.L., Cykhanski V.D., Chumakova N.L. [Analytical Department of the Institute of Geochemistry]. Journal of Analytical Chemistry, 2003, no. 12, vol. 58, pp. 1165-1173. Doi: 0.1023/B:JANC.0000008957. 71846.ca
Smagunova A.N., Pavlinsky G.V. [The Irkutsk school of x-ray spectrochemical analysis]. Journal of Analytical Chemistry, 2005, vol. 60, no. № 2, pp. 181-186. Doi: 10.1007/s10809-005-0058-1
Filippov M.N. [Mikhail Arnol’dovich Blokhin (1908-1995)]. Tez. Dokl. VI Vserossiyskoy konferencii po RSA [Abstr. reports VI All-Rusian Conference at the XRF], 2008, Krasnodar: Kuban State University, pp. 3-8 (in Russian).
Laputina I.P. [On the history of the X-ray spectral analysis group of the Institute of Geology of Ore deposits, Petrography, Mineralogy and Geochemistry (IGEM) of the Russian Academy of Sciences (RSMA LLMV IGEM RAS)]. Analitika i kontrol’
[Analytics and control], 2009, vol. 13, no. 4, pp. 213-215 (in Russian).
Revenko A., Hoffmann P. Editorial. X-Ray Spectrom., 2010, vol. 39, no. 1, pp. 1-2.
Smagunova A.N. [Development of X-ray fluorescence analysis]. In the book: Analytical chemists about themselves and their science / Eds.-comps. Yu.A. Zolotov, V.A. Shaposhnik, 2011, M.: Book House "Librokom". pp. 237-266.
Ilyin N.P. [X-ray spectral microanalysis methods]. In the book: Analytical chemists about themselves and their science / Eds.-comps. Yu.A. Zolotov, V.A. Shaposhnik, 2011, M.: Book House "Librokom". pp. 267-303.
Lavrent’ev Yu.G. [Scientic conferences on X-ray spectroscopy and to the X-Ray Spectral analysis as reflection of formation and development process of the Soviet/Russian X-Ray Spectral microanalysis]. Analitika i kontrol’ [Analytics
and control], 2013, vol. 17, no. 3, pp. 252-274 (in Russian). Doi: 10.15826/analitika.2013.17.3.001
Revenko A.G. [On the 75th anniversary of prof. V.P. Afonin’s birth]. Analitika i kontrol’ [Analytics and Control], 2013, vol. 17, no. 3, pp. 358-364 (in Russian). Doi:10.15826/analitika.2013.17.3.014
Smagunova A.N., Revenko A.G. Development of domestic X-ray fluorescence analysis (according to the materials of conferences). Journal of Analytical Chemistry, 2014. vol. 69, no. 3, pp. 316-332. Doi: 10.7868/S0044450214010149
Revenko A.G. [Meteor in the sky]. [Muradin Kumakhov: Ahead of time. Life and creativity]. Comps. M.G. Kumakhov, A.M. Kumakhov, Nalchik: Elbrus, 2016, pp. 109-116 (in Russian).
Brytov I.A. [Nikolay Ivanovich Komyak, organizer of Russian X-ray instrument making, scientist and person (for the 90th anniversary)]. Nauchnoe priborostroenie [Sci. Instrum. Making], 2018, vol. 28, no. 4, pp. 21-23 (in Russian).
Revenko A.G., Duymakaev Sh.I. [85th birthday anniversary of Antonina Nikonovna Smagunova]. Analitika i kontrol’ [Analytics and control], 2019, vol. 23, no. 2, pp. 274-290 (in Russian).
Mazalov L.N. Rentgenovskie spektry i khimicheskaia sviaz' [X-ray spectra and chemical bonding]. 1982, Novosibirsk: Science, 111 p. (in Russian)
Mazalov L.N. Rentgenovskie spektry [X-ray spectra]. 2003. Novosibirsk: INCh SB RAS, 329 p. (in Russian)
Mazalov L. The possibilities of X-ray spectroscopy. Science in Siberia. 1998 (May 15). no. 18(2154) (In Russian).
Lavrent’ev Yu.G., Weinstein E.E. [Influence of instrumental error on the accuracy and sensitivity of X-ray spectral analysis. Message 1.] Zhurn. Analyt. Chem. [Journal of Analytical Chemistry], 1965, vol. 20, no. 9, p. 918-926 (in Russian).
Lavrent’ev Yu.G., Weinstein E.E. [Influence of instrumental error on the accuracy and sensitivity of X-ray spectral analysis. Message II]. Zhurn. Analyt. Chem. [Journal of Analytical Chemistry], 1965, vol. 20, no. 10, p. 1033-1037 (in Russian).
Weinstein E.E., Lavrent’ev Yu.G. [Current state of X-ray spectral fluorescence determination of trace elements and prospects for its development (review)]. Zhurn. Analyt. Chem. [Journal of Analytical Chemistry],1966, vol. 21, no. 4, p. 463-472 (in Russian).
Lavrent’ev Yu.G., Weinstein E.E. [Evaluation of the sensitivity limit for X-ray spectral fluorescence analysis]. Apparatura i metody rentgenovskogo analiza [Equipment and methods of X-ray analysis], L., Mashinostroenie Publ., 1968, Issue 3, pp. 3-18.
Lavrent’ev Yu.G., Weinstein E.E. [Optimal conditions for X-ray spectral fluorescence analysis with preliminary concentration of trace elements]. Zavodskaia laboratoriia [Industrial laboratory], 1969, vol. 35, no. 9, pp. 1063-1067.
Lavrent’ev Yu.G. [Selection of sample dilution conditions for X-ray spectral fluorescence analysis]. Zavodskaia laboratoriia [Industrial laboratory], 1969, vol. 35, no. 12, pp. 1452-1454.
Lavrent’ev Yu.G. [Development of X-ray spectral microanalysis at the institute]. In sb. "Institute of Geology and Geophysics SB (USSR Academy of Sciences and RAS) in the memoirs of veteran employees of the institute: Research teams, people, events, facts, an anthology of amateur poetry of different years]. SB RAS, V.S. Sobolev Institute of Geology and Mineralogy, A.A. Trofimuk Institute of Oil and Gas Geology and Geophysics. 2013. Novosibirsk: Publishing House "Geo", INGG SB, pp. 319-322 (in Russian).
Vasiliev V.I., Lavrent’ev Yu.G. [The discovery of onophrite, a selenium-containing variety of black mercury sulfide, in mercury ores of the Altai-Sayan region]. Doklady Akademii nauk SSSR [Reports of the USSR Academy of Sciences], 1968, vol. 182, no. 2, pp. 430-433 (in Russian).
Vasiliev V.I., Lavrent’ev Yu.G. [A new mercury-containing variety of sphalerite]. Doklady Akademii nauk SSSR [Reports of the USSR Academy of Sciences], 1969, vol. 186, no. 4, pp. 911-913 (in Russian).
Sotnikov V.I., Nikitina E.I., Lavrent'ev Yu.G., Semenov V.I. [Application of X-ray spectral microanalysis to the study of the compositional features of accessory minerals]. Geologiya i Geofizika [Geology and Geophysics], 1970, no. 9, pp. 43-49 (in Russian).
Sobolev N.V., Bartoshinsky Z.V., Efimova E.S., Lavrent’ev Yu.G., Pospelova L.N. [Association olivine - garnet - chrome diopside from the Yakut diamond]. Doklady Akademii nauk SSSR [Reports of the USSR Academy of Sciences], 1970, vol. 192, no. 6, pp. 1349-1352 (in Russian).
Godovikov A.A., Kochetkova K.V., Lavrent’ev Yu.G. [Bismuth sulftellurides from the Sokhondo deposit]. Zapiski Vsesoiuznogo mineralogicheskogo obshchestva [Notes of the All-Union Mineralogical Society], 1971, vol. 100, no. 3, pp. 257-265 (in Russian).
Vasiliev V.I., Lavrent’ev Yu.G. [Faded ores of mercury deposits]. Geologiia i Geofizika [Geology and Geophysics], 1977, no. 3, pp. 56-63 (in Russian).
Vasiliev V.I., Lavrent’ev Yu.G., Palchik N.A. [Shahovite - Hg8Sb2O13 - a new hypergene mineral]. Geologiia i Geofizika [Geology and Geophysics], 1980, no. 11, pp. 128-132 (in Russian).
Lavrent’ev Yu.G., Vasiliev V.I. [X-ray spectral microanalysis of hypergene mercury minerals]. Geologiia i Geofizika [Geology and Geophysics], 1981, no. 11, pp. 70-76 (in Russian).
Lavrent’ev Yu.G., Kuznetsova A.I., Nesterenko G.V., Malikov Yu.I. [X-ray microanalysis of native gold]. Geologiia i Geofizika [Geology and Geophysics], 1982, no. 2, pp. 83-87 (in Russian).
Afonin V.P., Perfilieva L.A., Lavrent’ev Yu.G. [Program for calculating on a computer the concentrations of elements in X-ray spectral microanalysis of samples of various chemical composition] Ezhegodnik – 1970, Irkutsk, 1971, Sibirskii Institut geokhimii Sibirskogo otdeleniia AN SSSR [Yearbook – 1970, Siberian Institute of Geochemistry, Siberian Branch of the USSR Academy of Sciences], Irkutsk, 1971, pp. 398-401 (in Russian).
Lavrent’ev Yu.G., Afonin V.P., Berdichevsky G.V., Chernetskaya N.A., Pospelova L.N. [Program for calculating the results of quantitative X-ray spectral microanalysis of multicomponent samples]. Apparatura i metody rentgenovskogo analiza [Equipment and methods of X-ray analysis], L.: Mashinostroenie Publ., 1974, Issue 13, pp. 215-228 (in Russian).
Lavrent’ev Yu.G., Berdichevsky G.V., Chernyavsky L.I., Kuznetsova A.I. ["Karat" is a program for calculating concentrations in quantitative X-ray spectral microanalysis]. Apparatura i metody rentgenovskogo analiza [Equipment and methods of X-ray analysis], L.: Mashinostroenie Publ., 1980, Issue. 23, pp. 217-224 (in Russian).
Lavrent’ev Yu.G., Usova L.V. [New version of the "Karat" software for quantitative X-ray spectral microanalysis]. Zhurn. Analyt. Chem. [Journal of Analytical Chemistry], 1994, vol. 46, no. 5, pp. 462-468 (in Russian).
Vasiliev V.I., Lavrent’ev Yu.G. [New data on the composition of eglestonite]. Doklady Akademii nauk SSSR [Reports of the USSR Academy of Sciences], 1986, vol. 287, no. 4, pp. 960-963. (in Russian)
Vasiliev V.I., Lavrent’ev Yu.G. [Eglestonite bromide Hg4(Cl,Br,I)2O – a new type of mercury oxychloride Hg4Cl2O]. Geologiia i Geofizika [Geology and Geophysics], 1987, no. 3, pp. 117-121 (in Russian).
Lavrent’ev Yu.G., Usova L.V., Kuznetsova A.I., Letov S.V. [X-ray spectral quantometric microanalysis of the most important minerals of kimberlites]. Geologiia i Geofizika [Geology and Geophysics], 1987, no. 5, pp. 75-81 (in Russian).
Lavrent’ev Yu.G., Usova L.V. [Selection of the optimal method for calculating correction factors for X-ray spectral microanalysis of rock-forming minerals]. Zhurn. Analyt. Chem. [Journal of Analytical Chemistry], 1996, vol. 51, no. 3, pp. 323-331 (in Russian).
Korolyuk V.N., Lavrent'ev Yu.G., Reznitskii L.Z. Quantitative electron probe microanalysis of oxygen in compounds with pentavalent vanadium: an ultrastrong absorption phenomenon. X-Ray Spectrom., 2000, vol. 29, no. 6, pp. 434-437. Doi: 10.1002/1097-4539(200011/12)29:6<434::AID-XRS449>3.0.CO;2-N
Korolyuk V.N., Usova L.V., Nigmatulina E.N. Accuracy in the Determination of the Compositions of Main Rockforming Silicates and Oxides on a JXA-8100 Microanalyzer]. Journal of Analytical Chemistry, 2009, vol. 64, no. 10, pp. 1042-1046. Doi: 10.1134/S1061934809100128
Korolyuk V.N., Lavrent’ev Yu.G., Usova L.V., Nigmatulina E.N. [Some features of X-ray registration using a JXA-8100 electron-probe microanalyzer]. Journal of Analytical Chemistry, 2010, vol. 65, no. 3, pp. 249-254. Doi: 10.1134/S106193481003007X
Korolyuk V.N., Nigmatulina E.N. Recording lead Mα line in rare-earth phosphates using a JEOL JXA-8100 microanalyser. Journal of Analytical Chemistry, 2013, vol. 68, no. 9, pp. 781-789. Doi: 10.1134/S1061934813090062
Lavrent’ev Yu.G., Korolyuk V.N., Usova L.V., Nigmatulina E.N. [X-ray spectral microanalysis of rock-forming minerals with a JXA-8100 microanalyzer]. Geologiia i Geofizika [Geology and Geophysics], 2015, vol. 56, no. 10, pp.1813-1824 (in Russian). Doi: 10.15372/GiG20151005
Kulikova I.M., Nabelkin O.A., Lavrent'ev Yu.G., Ivanov V.A. [Features of X-ray spectral microanalysis of nitrogen-containing compounds]. Zavodskaia laboratoriia, Diagnostika materialov [Industrial laboratory, Diagnostics of materials], 2019, vol. 85, no. 11, pp. 5-18 (in Russian). Doi: 10.26896/1028-6861-2019-85-11-5-18
Lavrent’ev Yu.G., Usova L.V. The sum of the concentrations of components as an indicator of the quality of X-ray microanalysis of minerals. Geologiya i Geofizika [Geology and Geophysics], 2018, vol.59, no. 11, pp. 1827-1835 (in Russian). Doi: 10.15372/GiG20181106
Lavrent’ev Yu.G., Karmanov N.S., Usova L.V. [Electron probe microanalysis of minerals: microanalyzer or scanning electron microscope?] Geologiia i Geofizika [Geology and Geophysics], 2015, vol. 56, no. 8, pp.1473-1482. Doi: 10.15372/GiG20150806
Sinyakova E.F., Kosyakov V.I., Borisenko A.S., Karmanov N.S. [Behavior of noble metals during fractional crystallization of Cu-Fe-Ni- (Pt, Pd, Rh, Ir, Ru, Ag, Au, Te) sulfide melts]. Geologiia i Geofizika [Geology and Geophysics], 2019, vol. 60., no. 6, pp. 820-842. Doi: 10.15372/RGG2019050
Dobretsov N.L., Simonov V.A., Kotlyarov A.V., Karmanov N.S. [Physicochemical parameters of magmatism of the Uksichan and Ichinsky volcanoes (Sredinnyi ridge, Kamchatka): data on melt inclusions]. Geologiia i Geofizika [Geology and Geophysics], 2019, vol. 60, no. 10, pp.1353-1383 (in Russian). Doi: 10.15372/RGG2019100
Pavlova L.A. [Development of X-ray electron probe microanalysis in Siberia]. Journal of Analytical Chemistry, 2008, vol. 63, no. 12, pp. 1199-1205. Doi: 10.1134/S1061934808120101
Pavlova L.A. Contribution of Siberian researchers to the development of electron probe X-ray microanalysis. X-Ray Spectrom., 2010, vol. 39, no. 1, pp. 3–11. Doi: 10.1002/xrs.1228
Lavrent’ev Yu.G. Electron probe analysis in geology / In the book: “Chemical analysis in geology and geochemistry”. Novosibirsk: Academic Publishing House "Geo", 2016, 622 p. Ch. 14, pp. 298-317.
Kulipanov G.N., Kuzin M.V., Kochubej D.I., Baryshev V.B. Preface. Nucl. Instrum. Methods Phys. Res. 2001, vol. 470A, pp. VII-X.
Kulipanov G.N., Skrinsky A.N. [The use of synchrotron radiation: state and prospects]. Uspekhi Fizicheskih Nauk [Progress Physical Sciences]. 1977, vol. 122, no. 3, pp. 369-418 (in Russian).
Revenko A.G. Rentgenospektral’nyi fluorestsentnyi analiz prirodnykh materialov [X-ray Spectral Fluorescence Analysis of Natural Materials]. Novosibirsk: Nauka, 1994. 264 p. (in Russian).
Revenko A.G. Rentgenofluorestsentnyi analiz: sostoianie i tendenttsii razvitiia (obzor) [X-ray Fluorescence Analysis: State and Development Trends (review). Zavodskaia laboratoriia [Industrial laboratory], 2000, vol. 66, no. 10, pp. 3-19.
Trunova V.A. X-ray fluorescence analysis with excitation by synchrotron radiation - a methodology for use in the study of specific objects. Dokt. diss. chem. sci.: 02.00.02., Irkutsk, 2018, 215 p. (in Russian).
Vazina A.A., Gerasimov V.S., Gorbunova N.P., Sergienko P.M., Shelestova V.M., Nesterikhin Yu., Baryshev V.B., Zolotaryov V.K., Kulipanov G.N., Trunova V.A. Non-invasive methods for express analysis of biological objects based on elemental analysis using synchrotron radiation on hair samples from animals and patients. Nucl. Instrum. and Meth. in Phys. Res., 1998, vol. 405A, pp. 454-458. Doi: 10.1016/S0168-9002(97)00172-1
Kolmogorov Y., Kovaleva V., Gonchar A. Analysis of trace elements in scalp hair of healthy people, hyperplasia and breast cancer patients with XRF method. Nucl. Instrum. and Meth. in Phys. Res., 2000, vol. 448A, no. 1-2, pp. 457-460. Doi: 10.1016/S0168-9002(00)00236-9
Gonchar A.M., Kolmogorov U.P., Gladkikh E.A., Shuvaeva O.V., Beisel N.F., Kolosova N.G. X-ray fluorescent analysis and atomic spectrometry for the bone's elemental composition determination. Nucl. Instrum. and Meth. in Phys. Res., 2005, vol. 543A, no. 1, pp. 271-273. Doi: 10.1016/j.nima.2005.01.239
Khramova E.P., Boyarskikh I.G., Chankina O.V., Kutsenogii K.P. SR XRF Analysis for Studying Plants in an Area of Geological Heterogeneity. Poverkhnost’. Rentgenovskie, Sinkhrotronnye i Neitronnye Issledovaniia [J. of Surf. Invest. Xray, Synchrotron and Neutron Techniques], 2012, vol. 6, no. 3, pp. 454–457. Doi: 10.1134/S1027451012050096
Okuneva G.N., Karas’kov F.M., Chernyavsky A.M., Loginova I.Yu., Levicheva E.N., Trunova V.A., Zvereva V.V., Volkov A.M., Kliver E.E., Zheleznyak S.I., Repezin S.A., Al’tov S.A., Vlasov Yu.A., Tarasenko O.A. Khimicheskie elementy v serdechno-sosudistoi sisteme kardiokhirurgicheskikh bol'nykh [Chemical elements in the cardiovascular system of cardiac surgery patients]. Novosibirsk, Academic Publ. "Geo", 2010, 183 p. (in Russian).
Okuneva G.N., Karaskov A.M., Trunova V.A., Zvereva V.V., Kliever Ye.E., Volkov A.M., Vlasov Yu.A. Chemical Elements and Structural/Molecular Properties of Myocardium in Infants with Transposition of Great Arteries. Congenital Heart Disease - Selected Aspects, 2012, Ch. 15, pp. 331-348.
Baryshev V.B., Kulipanov G.N., Zaitsev E.V., Terekhov Ya.V., Kalyuzhny V.I. [Highly sensitive X-ray fluorescence analysis of geological samples using synchrotron radiation]. Zhurn. Analyt. Chem. [Journal of Analytical Chemistry], 1987, vol. 42, no. 2, pp. 232-240 (in Russian).
Gilbert A.E., Koz’menko O.A., Baryshev V.B., Zolotarev K.V., Kulipanov G.N. [The use of synchrotron radiation for the determination of rare earth elements in rocks]. Zhurn. Analyt. Chem. [Journal of Analytical Chemistry],1987, vol. 42, no. 3, pp. 477-485 (in Russian).
Trounova V.A., Bobrov V.A., Zolotarev K.V., Pampura V.D. Synchrotron Radiation X-Ray Fluorescence Study of the Compositional Homogeneity of a Sediment Core from Lake Baikal. X-Ray Spectrom., 1996, vol. 25, no. 2, pp. 55–59.
Stepanova O.G., Trunova, V.A., Zvereva, V.V., Melgunov M.S., Fedotov A.P. Reconstruction of glacier fluctuations in the East Sayan, Baikalsky and Kodar Ridges (East Siberia, Russia) during the last 210 years based on high-resolution geochemical proxies from proglacial lake bottom sediments. Environ. Earth Sci., 2015, vol. 74, no. 3, pp. 2029-2040. Doi: 10.1007/s12665-015-4457-9
Daryin A.V., Zolotarev K.V., Kalugin I.A., Maksimova N.V. Application of SRXRF Analysis for Definition of Microelement Composition of Bottom Sediments from Hovsogol Lake (Mongolia). Search Geochemical Indicators for Processes of Sedimentation and Paleoclimate Variations in Baikal Rift Zone. Poverkhnost’. Rentgenovskie, Sinkhrotronnye i Neitronnye Issledovaniia [J. of Surf. Invest. Xray, Synchrotron and Neutron Techniques], 2003, no. 12, pp. 45-48.
Sokolovskaya I.P., Trounova V.A., Kiprianova L.M. The investigation of element distributions in some aquatic higher plants and bottom sediments of Novosibirsk reservoir (data by SR-XRF techniques). Nucl. Instr. Meth. Phys. Res., 2000, vol. 448A, p. 449 – 452. Doi: 10.1016/0168-9002(00)00233-3
Goldberg E.L., Gorbarenko S.A., Shaporenko A.D., Phedorin M.A.,
Artemov A.V., Bosin A.A., Zolotarev K.V. SRXFA for element compositions of bottom sediments from the Okhotsk Sea. Nucl. Instr. Meth. Phys. Res., 2005, vol. 543A, pp. 280-283. Doi: 10.1016/j.nima.2005.01.241
Bazarova E.P., Markova Yu.N., Zolotarev K.V., Rakshun Ya.V, Ushchapovskaya Z.F. First Geochemical Data on Loose Sediments in the Kan-i-Gut Cave Mine (Central Asia) by Synchrotron Radiation XRF Analysis. J. of Surf. Invest. X-ray, Synchrotron and Neutron Techniques, 2016, vol. 10, no. 2, pp. 361–364.
Zvereva V.V., Trunova V.A., Sorokoletov D.S., Polosmak N.V. Mercury in archeological hair samples from Хiongnu burials (Noin-Ula, Mongolia): SR XRF and CXRM analysis. X-ray Spectrom., 2017, vol. 46, no. 6, pp. 554-562. Doi: 10.1002/xrs.2798
Polosmak N.V., Trunova V.A. Hairs from Pazyryk graves (research method - X-ray fluorescence analysis using SR). Arkheol. Etnogr. Antropol. Evrasiya, 2004, no. 1(13), pp. 73–81.
Trunova V., Zvereva V., Polosmak N., Kochubey D., Kriventsov V., Kuper K. Investigation of Organic Materials from the ‘Royal’ Burials of Xiongnu (Noin-Ula, Mongolia) by SRXRF and XAFS Methods. Archaeometry, 2015, vol. 57, no. 6, pp. 1060-1077. Doi: 10.1111/arcm.12109
Trunova V.A., Danilovich V.S., Baryshev V.B., Zolotarev K.V. Application of SR-XFA for identification of the basic composition of high-temperature superconductors. Nucl. Instrum. Meth. Phys. Res., 1991, vol. 308A, no. 1-2, p. 321-324. Doi: 10.1016/0168-9002(91)90659-E
Trounova V.A., Danilovich V.S., Zolotarev K.V., Predtechensii M.R., Bobrinok O.F. Application of synchrotron radiation XRF analysis in high-temperature superconducting thin-film technology. X-Ray Spectrom., 1994, vol. 23, no. 4, pp. 187-189. Doi: 10.1002/xrs.1300230410
Kudryashova A.F., Tarasov L.S., Ulyanov A.A., Baryshev V.B. Some methodical peculiarities of analysis of small-mass samples by SRXFA. Nucl. Instrum. Meth. Phys. Res. 1989, vol. 282A, no. 2-3, pp. 673-676. Doi: 10.1016/0168-9002(89)90079-X
Tarasov L.S., Kudryashova A.F., Ulyanov A.A., Baryshev V.B., Bobrov V.A., Shipitsyn Yu.G., Vertman E.G., Sudyko A.F. Geochemical identification of mare-type basalt groups from a lunar highland region (by INAA and SRXFA). Nucl. Instrum. Meth. Phys. Res., 1989, vol. 282A, no. 2-3, pp. 669-672. Doi: 10.1016/0168-9002(89)90078-8
Tarasov L.S., Kudryashova A.F., Ulyanov A.A., Baryshev V.B., Zolotarev K.V. Geochemistry of rare elements in lunar basalt rocks based on SRXFA. Nucl. Instrum. Meth. Phys. Res. 1989, vol. 282A, no. 2-3, pp. 677-683. Doi: 10.1016/0168-9002(89)90080-6
Tarasov L.S., Kudryashova A.F., Ulyanov A.A., Baryshev V.B., Zolotarev K.V. Trace element distribution in lunar rocks of various titanium content by SR-XFA data. Nucl. Instrum. Meth. Phys. Res., 1995, vol. 359A, no. 1-2, pp. 312-316. Doi: 10.1016/0168-9002(94)01658-5
Tarasov L.S., Kudryashova A.F., Ulyanov A.A., Baryshev V.B., Zolotarev K.V. v Geochemistry of trace elements in the highland lunar rocks based on SRXFA data. Nucl. Instrum. Meth. Phys. Res., 1998, vol. 405A, no. 2-3. pp. 590-598. Doi: 10.1016/S0168-9002(96)01124-2
Tarasov L.S., Kudryashova A.F., Ulyanov A.A., Baryshev V.B., Zolotarev K.V. Particularities of rare element distribution in high-aluminium basalts from mare and highland regions of the Moon (based on SR-XFA data). Nucl. Instrum. Meth. Phys. Res., 2000, vol. 448A, no. 1-2. pp. 376-383. Doi: 10.1016/S0168-9002(99)00695-6
Baryshev V.B., Kudryashov A.F., Tarasov L.S., Ulyanov A.A., Zolotarev K.V. Geochemistry of rare elements in different types of lunar rocks (based on XFA-SR data). Nucl. Instrum. Meth. Phys. Res., 2001, vol. 470A, no. 1-2, pp. 422–425. Doi: 10.1016/S0168-9002(01)01089-0
Zolotarev K.V., Goldberg E.L., Kondratyev V.I., Kulipanov G.N., Miginsky E.G., Tsukanov V.M., Phedorin M.A., Kolmogorov Yu.P. Scanning SR-XRF beamline for analysis of bottom sediments. Nucl. Instrum. Methods A, 2001, vol. 470, no. 1-2, pp. 376-379. Doi: 10.1016/S0168-9002(01)01073-7
Phedorin M.A., Bobrov V.A., Zolotarev K.V. SR-XFA on VEPP-3 of the bottom sediments of Lake Baikal to perform a paleoclimatic reconstruction. Nucl. Instrum. Meth. Phys. Res. A, 1998, vol. 405, no. 2-3, pp. 560-568. Doi: 10.1016/S0168-9002(97)00177-0
Bobrov V.A., Kalugin I.A., Phedorin M.A. SRXFA of element composition of bottom sediments from Teletskoye Lake. Nucl. Instrum. Meth. Phys. Res. A, 1998, vol. 405, № 2-3, pp. 569-571. Doi:10.1016/S0168-9002(96)01057-1
Phedorin M.A., Bobrov V.A., Goldberg E.L., Navez J., Zolotaryov K.V., Grachev M.A. SR-XFA as a method of choice in the search of signals of changing palaeoclimates in the sediments of Lake Baikal, compared to INAA and ICP-MS. Nucl. Instrum. Meth. Phys. Res. A, 2000, vol. 448, no. 1-2, pp. 394-399. Doi: 10.1016/S0168-9002(99)00721-4
Phedorin M.A., Goldberg E.L., Grachev M.A., Levina O.L., Khlystov O.M., Dolbnya I.P. The comparison of biogenic silica, Br and Nd distributions in the sediments of Lake Baikal as proxies of changing paleoclimates of the last 480 kyr. Nucl. Instrum. Meth. Phys. Res. A, 2000, vol. 448, no. 1-2, pp. 400-406. Doi: 10.1016/S0168-9002(99)00726-3
Daryin A.V., Kalugin I.A., Maksimova N.V. et al. Use of a scanning XRF analysis on SR beams from VEPP-3 storage ring for research of core bottom sediments from Teletskoe Lake with the purpose of high resolution quantitative reconstruction of last millennium paleoclimate. Nucl. Instrum. Meth. Phys. Res. A, 2005, vol. 543, no. 1, pp. 255-258. Doi: 10.1016/j.nima.2005.01.217
Phedorun M.A., Goldberg E.L. Prediction of absolute concentrations of elements from SR XRF scan measurements of natural wet sediments. Nucl. Instrum. Meth. Phys. Res. A, 2005, vol. 543, no. 1, pp. 274-279. Doi: 10.1016/j.nima.2005.01.240
Goldberg E.L., Grachev M.A., Chebykin E.P., Phedorin M.A., Kalugin I.A., Khlystov O.M., Zolotarev K.V. Scanning SRXF analysis and isotopes of uranium series from bottom sediments of Siberian lakes for high-resolution climate reconstructions. Nucl. Instrum. Meth. Phys. Res. A, 2005, vol. 543, no. 1, pp. 250–254. Doi: 10.1016/j.nima.2005.01.216
Stepanova O.G., Trunova V.A., Zvereva V.V., Mel’gunov M.S., Petrovskii S.K., Krapivina S.M., Fedotov A.P. Reconstruction of the peretolchin glacier fluctuation (east sayan) during the 20th century inferred from the bottom sediments of proglacial lake Ekhoi. Geologiia i Geofizika [Geology and Geophysics]. 2015, vol. 56, no. 9, pp. 1621-1629. Doi: 10.15372/GiG20150904
Trunova V.A., Stepanova O.G., Zvereva V.V., Sidorina A.V., Melgunov M.S., Petrovskii S.K., Rakshun Ya.V., Fedotov A.P. Tracing recent glacial events in bottom sediments of a glacial lake (East Sayan Ridge, Russia) from high-resolution SR-XRF, ICP-MS, and FTIR records. X-Ray Spectrom., 2015, vol. 44, no. 4, pp. 255–262. Doi: 10.1002/xrs.2616
Fedotov A.P., Trunova V.A., Enushchenko I.V., Vorobyeva S.S., Stepano-
va O.G, Petrovskii S.K., Melgunov M.S., Zvereva V.V., Krapivina S.M., Zheleznyakova T.O. A 850-year record climate and vegetation changes in East Siberia (Russia), inferred from geochemical and biological proxies of lake sediments. Environ. Earth Sci., 2015, vol. 73, no. 12, pp. 7297-7314. Doi: 10.1007/s12665-014-3906-1
Stepanova O.G., Trunova V.A., Zvereva V.V., Melgunov M.S., Fedotov A.P. Reconstruction of glacier fluctuations in the East Sayan, Baikalsky and Kodar Ridges (East Siberia, Russia) during the last 210 years based on high-resolution geochemical proxies from proglacial lake bottom sediments. Environ. Earth Sci., 2015, vol. 74, no. 3, pp. 2029-2040. Doi: 10.1007/s12665-015-4457-9
Vorobyeva S.S., Trunova V.A., Stepanova O.G., Zvereva V.V., Petrovskii S.K., Melgunov M.S., Zheleznyakova T.O., Chechetkina L.G., Fedotov A.P. Impact of glacier changes on ecosystem of proglacial lakes in high mountain regions of East Siberia (Russia). Environ. Earth Sci., 2015, vol. 74, no. 3, pp 2055-2063. Doi: 10.1007/s12665-015-4164-6
Kumakhov M.A. Capillary optics and their use in X-ray analysis, X-Ray
Spectrom., 2000, vol. 29, no. 5, pp. 343–348. Doi: 10.1002/1097-4539(200009/10) 29:5<343::AID-XRS414>3.0.CO;2-S
Kumakhov M.A. Status of polycapillary optics and perspectives, Proc.
SPIE, 2002, vol. 4765, pp. 20–25. Doi: 10.1117/12.489770
Handbook of Practical X-Ray Fluorescence Analysis / Ed. by B. Beckhoff [et al.]. Berlin/Heidelberg: Springer, 2006. 863 p.
Revenko A.G. Specific features of X-ray fluorescence analysis techniques using capillary lenses and synchrotron radiation. Spectrochim. Acta, Part B, 2007, vol. 62, no. 7, pp. 567-576. Doi:10.1016/j.sab.2007.04.019
Trunova V.A., Zvereva V.V. X-Ray fluorescent analysis using synchrotron radiation: Subjects of research. J. Struct. Chem., 2016, vol. 57, no. 7, pp. 1327-1333. Doi: 10.1134/S0022476616070052
Sorokoletov D.S., Rakshun Ya.V., Dar'in F.A. [Hardware functions of a polycapillary lens and a confocal X-ray microscope during restructuring of its confocal volume]. Avtometriya [Autometry], 2015, no. 3, p. 94-10 (in Russian).
DOI: https://doi.org/10.15826/analitika.2021.25.2.006
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