ВЛИЯНИЕ ПРИРОДЫ МОДИФИКАТОРА НА ЭФФЕКТИВНОСТЬ КОНЦЕНТРИРОВАНИЯ РУТИНА И КВЕРЦЕТИНА НА НАНОЧАСТИЦАХ МАГНЕТИТА
Аннотация
Методом химического соосаждения синтезированы магнитные наночастицы (МНЧ) магнетита, поверхность которых модифицирована диоксидом кремния, диоксидом кремния и полиэтиленимином и только полиэтиленимином. Полученные МНЧ охарактеризованы методами электрофоретического рассеяния света и просвечивающей электронной микроскопии. Показано, что на величину и знак дзета-потенциала МНЧ влияют природа модификатора и рН раствора. Изучено влияние рН, количества сорбента, времени сорбции, способа перемешивания раствора и найдены оптимальные условия сорбции кверцетина и рутина. Установлено, что сорбция указанных флавоноидов количественно происходит на магнетите, модифицированном как SiO2@ПЭИ так и только ПЭИ, протекает за 10 мин, однако степень извлечения выше на МНЧ, модифицированных ПЭИ, которая для кверцетина и рутина составляет 98 % и 86 %, соответственно. Показано, что степень извлечения кверцетина и рутина при десорбции 4 мл 0.1 М NaOH в течение 20 минут составляет 62 и 56 процентов, соответственно.
Ключевые слова: магнетит, наночастицы, магнитная твердофазная экстракция, флавоноиды, кверцетин, рутин, концентрирование
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